Lanthanide single-molecule magnets
DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …
coordination compound could, at liquid-helium temperatures, retain magnetization for long …
Reading and writing single-atom magnets
The single-atom bit represents the ultimate limit of the classical approach to high-density
magnetic storage media. So far, the smallest individually addressable bistable magnetic bits …
magnetic storage media. So far, the smallest individually addressable bistable magnetic bits …
Two-coordinate Co (II) imido complexes as outstanding single-molecule magnets
The pursuit of single-molecule magnets (SMMs) with better performance urges new
molecular design that can endow SMMs larger magnetic anisotropy. Here we report that two …
molecular design that can endow SMMs larger magnetic anisotropy. Here we report that two …
Single ion magnets from 3d to 5f: developments and strategies
M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …
Understanding the magnetic anisotropy toward single-ion magnets
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …
preferentially after removal of the magnetic field below a certain temperature. The unique …
Strategies toward high-temperature lanthanide-based single-molecule magnets
L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …
magnetization blocking at the level of one molecule. In this paper, we examine the physical …
Luminescent single-molecule magnets based on lanthanides: Design strategies, recent advances and magneto-luminescent studies
Incorporation of two characters into one molecular entity is an effective way to afford
bifunctional molecule-based materials. Lanthanides serve as a group of preferable …
bifunctional molecule-based materials. Lanthanides serve as a group of preferable …
Taming Super-Reduced Bi23– Radicals with Rare Earth Cations
Here, we report the synthesis of two new sets of dibismuth-bridged rare earth molecules.
The first series contains a bridging diamagnetic Bi22–anion,(Cp* 2RE) 2 (μ-η2: η2-Bi2), 1 …
The first series contains a bridging diamagnetic Bi22–anion,(Cp* 2RE) 2 (μ-η2: η2-Bi2), 1 …
Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies
SG McAdams, AM Ariciu, AK Kostopoulos… - Coordination Chemistry …, 2017 - Elsevier
Over the past fifteen years or so, the study of f-element single-ion magnets (f-SIMs) has gone
from being a sub-discipline of molecular magnetism to an established field of research in its …
from being a sub-discipline of molecular magnetism to an established field of research in its …
Radical ligand-containing single-molecule magnets
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …
and processing; however, such applications require large spin relaxation barriers and …