Lanthanide single-molecule magnets

DN Woodruff, REP Winpenny, RA Layfield - Chemical reviews, 2013 - ACS Publications
In the early 1990s, great excitement followed the discovery that a molecular transition metal
coordination compound could, at liquid-helium temperatures, retain magnetization for long …

Reading and writing single-atom magnets

FD Natterer, K Yang, W Paul, P Willke, T Choi, T Greber… - Nature, 2017 - nature.com
The single-atom bit represents the ultimate limit of the classical approach to high-density
magnetic storage media. So far, the smallest individually addressable bistable magnetic bits …

Two-coordinate Co (II) imido complexes as outstanding single-molecule magnets

XN Yao, JZ Du, YQ Zhang, XB Leng… - Journal of the …, 2017 - ACS Publications
The pursuit of single-molecule magnets (SMMs) with better performance urges new
molecular design that can endow SMMs larger magnetic anisotropy. Here we report that two …

Single ion magnets from 3d to 5f: developments and strategies

M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …

Understanding the magnetic anisotropy toward single-ion magnets

YS Meng, SD Jiang, BW Wang… - Accounts of chemical …, 2016 - ACS Publications
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

Luminescent single-molecule magnets based on lanthanides: Design strategies, recent advances and magneto-luminescent studies

JH Jia, QW Li, YC Chen, JL Liu, ML Tong - Coordination Chemistry …, 2019 - Elsevier
Incorporation of two characters into one molecular entity is an effective way to afford
bifunctional molecule-based materials. Lanthanides serve as a group of preferable …

Taming Super-Reduced Bi23– Radicals with Rare Earth Cations

P Zhang, R Nabi, JK Staab, NF Chilton… - Journal of the American …, 2023 - ACS Publications
Here, we report the synthesis of two new sets of dibismuth-bridged rare earth molecules.
The first series contains a bridging diamagnetic Bi22–anion,(Cp* 2RE) 2 (μ-η2: η2-Bi2), 1 …

Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies

SG McAdams, AM Ariciu, AK Kostopoulos… - Coordination Chemistry …, 2017 - Elsevier
Over the past fifteen years or so, the study of f-element single-ion magnets (f-SIMs) has gone
from being a sub-discipline of molecular magnetism to an established field of research in its …

Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …