Cationic polymerization is a powerful strategy for the production of well-defined polymers
and advanced materials. In particular, the emergence of living cationic polymerization has …

Visible light-regulated metal-free polymerizations have attracted considerable attention for
macromolecular syntheses in recent years. However, few organic photocatalysts show high …

Photopolymerization is an energy‐saving and environmentally friendly technology and has
been widely applied and continuously developed in various fields since the mid‐20th …

By virtue of noninvasive regulations by light, photocontrolled polymerizations have attracted
considerable attention for the precision synthesis of macromolecules. However, a cationic …

Research on metal-free catalytic synthesis of polycaprolactone (PCL) is fueled by the many
practical needs for biodegradable and biocompatible materials. In this regard, the pursuit of …

The cationic polymerization of p‐methoxystyrene (pMOS) was carried out at 25° C using
pMOS· HCl and Sb (C6F5) 3. Under the condition of [pMOS· HCl]:[Sb (C6F5) 3]:[pMOS]= 10 …

A class of monophosphonium photocatalysts is developed via the assembly of phosphines
and alkynes, and demonstrated as efficient organic photoredox catalysts for the visible light …

The existing photo-induced electron/energy transfer reversible addition-fragmentation chain
transfer polymerization (PET-RAFT) systems using gC 3 N 4 as catalyst are complicated and …

The visible-light-induced cationic polymerization of isobutylene with a dimanganese
decacarbonyl (Mn2 (CO) 10)/diphenyl iodonium hexafluorophosphate (Ph2I+ PF6–) …

Living cationic polymerization of vinyl ethers (VEs) using diaryliodonium (DAI) salts as
organic Lewis acid catalysts was accelerated without loss of livingness via UV light …