Photo-and redox-driven artificial molecular motors

M Baroncini, S Silvi, A Credi - Chemical reviews, 2019 - ACS Publications
Directed motion at the nanoscale is a central attribute of life, and chemically driven motor
proteins are nature's choice to accomplish it. Motivated and inspired by such …

The future of molecular machines

I Aprahamian - ACS central science, 2020 - ACS Publications
Artificial molecular machines have captured the imagination of scientists and nonscientists
alike for decades now, given their clear potential to transform and enhance all aspects of …

Molecular pumps and motors

Y Feng, M Ovalle, JSW Seale, CK Lee… - Journal of the …, 2021 - ACS Publications
Pumps and motors are essential components of the world as we know it. From the complex
proteins that sustain our cells, to the mechanical marvels that power industries, much we …

Visible-light-driven rotation of molecular motors in discrete supramolecular metallacycles

ZT Shi, YX Hu, Z Hu, Q Zhang, SY Chen… - Journal of the …, 2020 - ACS Publications
The organization of molecular motors in supramolecular assemblies to allow the
amplification and transmission of motion and collective action is an important step toward …

[HTML][HTML] Pumps through the ages

Y Qiu, Y Feng, QH Guo, RD Astumian, JF Stoddart - Chem, 2020 - cell.com
Artificial molecular machines (AMMs) have profoundly enhanced scientists' capability to
manipulate the relative movements of components within molecules. Mechanically …

The burgeoning of mechanically interlocked molecules in chemistry

D Sluysmans, JF Stoddart - Trends in Chemistry, 2019 - cell.com
Mechanically interlocked molecules (MIMs), such as rotaxanes, catenanes, and molecular
knots, have attracted significant interest because of their unique properties originating from …

Structure property analysis of the solution and solid-state properties of bistable photochromic hydrazones

B Shao, H Qian, Q Li, I Aprahamian - Journal of the American …, 2019 - ACS Publications
The development of new photochromic compounds and the optimization of their
photophysical and switching properties are prerequisites for accessing new functions and …

Multitasking with chemical fuel: Dissipative formation of a pseudorotaxane rotor from five distinct components

A Ghosh, I Paul, M Schmittel - Journal of the American Chemical …, 2021 - ACS Publications
A 3-fold completive self-sorted library of dynamic motifs was integrated into the design of the
pseudorotaxane-based rotor [Zn (2· H+)(3)(4)] 2+ operating at k 298= 15.4 kHz. The …

Manipulating solid-state intramolecular motion toward controlled fluorescence patterns

S Liu, Y Cheng, Y Li, M Chen, JWY Lam, BZ Tang - ACS nano, 2020 - ACS Publications
Molecules have limited mobility in the solid state because of the strong intermolecular
interactions, and therefore, applications based on solid-state molecular motions are seldom …

Benchmark Dynamics of Dipolar Molecular Rotors in Fluorinated Metal‐Organic Frameworks

J Perego, CX Bezuidenhout, S Bracco… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Fluorinated Metal‐Organic Frameworks (MOFs), comprising a wheel‐shaped ligand
with geminal rotating fluorine atoms, produced benchmark mobility of correlated dipolar …