Three‐Axis Anisotropic Exchange Coupling in the Single‐Molecule Magnets NEt4[MnIII2(5‐Brsalen)2(MeOH)2MIII(CN)6] (M=Ru, Os)

J Dreiser, KS Pedersen, A Schnegg… - … A European Journal, 2013 - Wiley Online Library
We have investigated the single‐molecule magnets [MnIII2 (5‐Brsalen) 2 (MeOH) 2MIII (CN)
6] NEt4 (M= Os (1) and Ru (2); 5‐Brsalen= N, N′‐ethylenebis (5‐bromosalicylidene) …

Influence of structure on exchange strength and relaxation barrier in a series of Fe II Re IV (CN) 2 single-chain magnets

X Feng, TD Harris, JR Long - Chemical Science, 2011 - pubs.rsc.org
Cyano-bridged single-chain magnets of the type L4FeReCl4 (CN) 2, where L=
diethylformamide (DEF)(1), dibutylformamide (DBF)(2), dimethylformamide (DMF)(3) …

Towards multifunctional magnetic systems through molecular-programmed self assembly of Re (IV) metalloligands

J Martinez-Lillo, J Faus, F Lloret, M Julve - Coordination Chemistry Reviews, 2015 - Elsevier
The molecular-programmed approach based on the use as ligands of tailor-made
metalloligands containing stable six-coordinate rhenium (IV) as paramagnetic centres is …

Group 6 Complexes with Iron and Zinc Heterometals: Understanding the Structural, Spectroscopic, and Electrochemical Properties of a Complete Series of MM··· M …

M Nippe, E Bill, JF Berry - Inorganic chemistry, 2011 - ACS Publications
Binuclear quadruply bonded complexes Cr2 (dpa) 4 (1, dpa= 2, 2′-dipyridylamide), Mo2
(dpa) 4 (2), and W2 (dpa) 4 (3) react with anhydrous FeCl2, yielding heterometallic …

Manganese (II), iron (II), and mixed-metal metal–organic frameworks based on chains with mixed carboxylate and azide bridges: magnetic coupling and slow …

YQ Wang, Q Yue, Y Qi, K Wang, Q Sun… - Inorganic …, 2013 - ACS Publications
Mn (II) and Fe (II) compounds derived from azide and the zwitterionic 1-
carboxylatomethylpyridinium-4-carboxylate ligand are isomorphous three-dimensional …

Deciphering the origin of giant magnetic anisotropy and fast quantum tunnelling in Rhenium (IV) single-molecule magnets

SK Singh, G Rajaraman - Nature communications, 2016 - nature.com
Single-molecule magnets represent a promising route to achieve potential applications such
as high-density information storage and spintronics devices. Among others, 4 d/5 d elements …

New family of thiocyanate-bridged Re (IV)-SCN-M (II)(M= Ni, Co, Fe, and Mn) heterobimetallic compounds: synthesis, crystal structure, and magnetic properties

R Gonzalez, A Acosta, R Chiozzone, C Kremer… - Inorganic …, 2012 - ACS Publications
The heterobimetallic complexes of formula [(Me2phen) 2M (μ-NCS) Re (NCS) 5]· CH3CN
[Me2phen= 2, 9-dimethyl-1, 10-phenanthroline and M= Ni (1), Co (2), Fe (3), and Mn (4)] …

Effect of structural isomerism on magnetic dynamics: from single-molecule magnet to single-chain magnet

TT Wang, M Ren, SS Bao, B Liu, L Pi, ZS Cai… - Inorganic …, 2014 - ACS Publications
This Paper reports the first examples of O–P–O bridged Mn2 (salen) 2 (salen= N, N'-bis
(salicylidene) ethylenediamine) chain compounds, namely,[Mn2 (salen) 2 (2 …

Theoretical determination of spin Hamiltonians with isotropic and anisotropic magnetic interactions in transition metal and lanthanide complexes

R Maurice, C De Graaf, N Guihery - Physical Chemistry Chemical …, 2013 - pubs.rsc.org
The determination of anisotropic magnetic parameters is a task of both experimental and
theoretical interest. The added value of theoretical calculations can be crucial for analyzing …

Three coordination polymers based on 3-(3′, 5′-dicarboxylphenoxy) phthalic acid and auxiliary N-donor ligands: syntheses, structures, and highly selective sensing …

LN Wang, YH Zhang, S Jiang, ZZ Liu - CrystEngComm, 2019 - pubs.rsc.org
Three new coordination polymers derived from a 3-(3′, 5′-dicarboxylphenoxy) phthalic
acid (H4L) ligand have been constructed with Zn (II) and Cd (II) ions under hydrothermal …