Ferromagnetic coupling and spin canting behaviour in heterobimetallic Re IV M II/III (M= Co II/III, Ni II) species

J Martínez-Lillo, D Armentano, G De Munno… - Dalton …, 2013 - pubs.rsc.org
Three novel heterobimetallic Re (IV) compounds of formulae [ReBr4 (μ-ox) M (4, 7-Cl2phen)
2]· CH3CN· CH3NO2 [M= Co (II)(1) and Ni (II)(2)] and [ReBr4 (ox)] 3 [CoIII (5, 6-dmphen) 3] …

Syntheses, structures, and magnetic characterizations of cyanide-bridged Fe III Mn III chains constructed by mer-Fe (III) tricyanide and Mn (III) Schiff bases …

IY Yoo, DW Ryu, JH Yoon, AR Sohn, KS Lim… - Dalton …, 2012 - pubs.rsc.org
Five Fe (III) Mn (III) bimetallic compounds [Fe (iqc)(CN) 3][Mn (5-Xsalen)]· pMeOH· qMeCN·
rH2O [Hiqc= N-(quinolin-8-yl) isoquinoline-1-carboxamide; salen= N, N′-ethylenebis …

Towards understanding the magnetism of Os (iv) complexes: an ab initio insight

L Ungur, K Pallitsch, ZA AlOthman… - Dalton …, 2021 - pubs.rsc.org
The magnetism of a recently synthesized trans-[OsIVCl4 (κN1-Hind) 2] complex (5d4-
system), where Hind= 2H-indazole, was studied experimentally and theoretically. Relativistic …

Theoretical insights into the origin of magnetic exchange and magnetic anisotropy in {Re IV–M II}(M= Mn, Fe, Co, Ni and Cu) single chain magnets

SK Singh, KR Vignesh, V Archana… - Dalton Transactions, 2016 - pubs.rsc.org
Density functional calculations have been performed on a series of {ReIV–MII}(M= Mn (1),
Fe (2), Co (3), Ni (4), Cu (5)) complexes to compute the magnetic exchange interaction …

Synthesis, structures and magnetism of heterodinuclear Ni–Ln complexes: field-induced single-molecule magnet behavior in the dysprosium analogue

XY Lu, YQ Liu, XW Deng, ZX Zhu, MX Yao… - New Journal of …, 2015 - pubs.rsc.org
Using the hexafluoroacetylacetonato (hfac), azide anion and compartmental Schiff-base
ligand H2valpn (H2valpn= 1, 3-propanediylbis (2-iminomethylene-6-methoxy-phenol), three …

First magnets based on thiocyanato-bridges

M Mousavi, V Béreau, C Duhayon… - Chemical …, 2012 - pubs.rsc.org
2-D NCS-bridged {3d–4d} molecule-based magnets, formed by reaction of [MoIII (NCS) 6]
3− with either NiII or CoII complexes, have been found to exhibit magnetic ordering with TC …

Magneto-Structural Correlations in a Family of FeIIReIV(CN)2 Single-Chain Magnets: Density Functional Theory and Ab Initio Calculations

YQ Zhang, CL Luo, XB Wu, BW Wang… - Inorganic chemistry, 2014 - ACS Publications
Until now, the expressions of the anisotropic energy barriers Δξ and ΔA, using the uniaxial
magnetic anisotropy D, the intrachain coupling strength J, and the high-spin ground state S …

Heterobimetallic coordination polymers involving 3d metal complexes and heavier transition metals cyanometallates

EV Peresypkina, DG Samsonenko… - Journal of Solid State …, 2015 - Elsevier
The results of the first steps in the design of coordination polymers based on penta-and
heptacyanometallates of heavier d transitions metals are presented. The 2D structure of the …

Synthesis, Crystal Structures, and Magnetic Properties of Cyanide-Bridged WVMnIII Anionic Coordination Polymers Containing Divalent Cationic Moieties: Slow …

JH Yoon, KS Lim, DW Ryu, WR Lee, SW Yoon… - Inorganic …, 2014 - ACS Publications
Two trimetallic coordination complexes were prepared by self-assembly of [W (CN) 8] 3–and
the Mn (III) Schiff base followed by the addition of a Zn (II) or Fe (II) cationic unit. The …

Tuning the interactions from antiferro-to ferro-magnetic by molecular tailoring and manipulating

X Zhang, B Li, J Tang, J Tian, G Huang, J Zhang - Dalton Transactions, 2013 - pubs.rsc.org
Four novel CuII complexes {Na [Cu4 (hmp) 4 (CHOO) 3](ClO4) 2· H2O} n (1),[Cu8 (hmp) 8
(CH3COO) 6](ClO4) 2 (2),[Cu4 (hmp) 4 (CH3CN) 2 (ClO4) 2 (H2O) 2](ClO4) 2 (3), and [Cu4 …