Liquid chromatography coupled to isotope ratio mass spectrometry (LC-IRMS): a review

M Perini, L Bontempo - TrAC Trends in Analytical Chemistry, 2022 - Elsevier
An accurate analysis of the composition of stable isotopes is today an increasingly important
requirement in various fields of science (from the environmental to the medical field). Since …

Organic proxies in speleothems–New developments, advantages and limitations

AJ Blyth, A Hartland, A Baker - Quaternary Science Reviews, 2016 - Elsevier
Research into organic matter in speleothems has progressed recently to encompass new
analytical approaches and applications, which offer increased potential in areas such as …

A 9000-year carbon isotopic record of acid-soluble organic matter in a stalagmite from Heshang Cave, central China: Paleoclimate implications

X Li, C Hu, J Huang, S Xie, A Baker - Chemical Geology, 2014 - Elsevier
Organic matter preserved in speleothems has the potential to reflect the changes of the
overlying vegetation and soil ecosystem. Here we report the first near 50-yr-resolution acid …

Organic characterisation of cave drip water by LC-OCD and fluorescence analysis

H Rutlidge, MS Andersen, A Baker, KJ Chinu… - … et Cosmochimica Acta, 2015 - Elsevier
Abstract Cathedral Cave, Wellington, Australia, is a natural laboratory for studying water
movement and geochemical processes in the unsaturated zone by using artificial irrigation …

[HTML][HTML] Investigating the application of organic geochemical techniques to tropical Anjohibe (Madagascar) stalagmites

RR Dawson, IS Castañeda, SJ Burns, JM Salacup… - Organic …, 2024 - Elsevier
Speleothem stable carbon isotopes (δ 13 C carb) are used to reconstruct past environments,
but are a complex signal of karst, soil and plant processes. To help untangle these signals …

Quantification of low molecular weight fatty acids in cave drip water and speleothems using HPLC-ESI-IT/MS—development and validation of a selective method

JM Bosle, SA Mischel, AL Schulze, D Scholz… - Analytical and …, 2014 - Springer
This study presents a novel method for the analysis of low molecular weight (LMW) fatty
acids in cave drip water and speleothems. The method development included optimization …

A new perspective on the δ13C signal preserved in speleothems using LC–IRMS analysis of bulk organic matter and compound specific stable isotope analysis

AJ Blyth, CI Smith, RN Drysdale - Quaternary Science Reviews, 2013 - Elsevier
The analysis of δ 13 C in speleothem calcite is established as a palaeoenvironmental proxy,
but records can often be complex to interpret due to multiple controls on the signal. Here we …

Molecular signatures of dissolved organic matter in a tropical karst system

FA Lechleitner, T Dittmar, JUL Baldini, KM Prufer… - Organic …, 2017 - Elsevier
Karst areas are widespread landforms present on all continents, formed by the dissolution of
carbonate or evaporite host rock. Little is known about the composition and nature of …

A novel high‐temperature combustion based system for stable isotope analysis of dissolved organic carbon in aqueous samples. II: optimization and assessment of …

F Kirkels, C Cerli, E Federherr, J Gao… - … in Mass Spectrometry, 2014 - Wiley Online Library
RATIONALE Dissolved organic carbon (DOC) plays an important role in carbon cycling,
making precise and routine measurement of δ13C values and DOC concentration highly …

Geochemical mapping of organic carbon in stalagmites using liquid-phase and solid-phase fluorescence

M Quiers, Y Perrette, E Chalmin, B Fanget… - Chemical Geology, 2015 - Elsevier
The soil-derived organic matter incorporated in speleothems provides a proxy for the
impacts of climate and environmental changes on the surrounding catchment. These …