Aerobic oxidative functionalization of indoles

S Liu, F Zhao, X Chen, GJ Deng… - Advanced Synthesis & …, 2020 - Wiley Online Library
The synthetic methodology for direct indole functionalizations is of great significance in
indole chemistry and has been intensively investigated in the last few decades. From the …

Recent advances in graphene oxide catalyzed organic transformations

F Gao, S Zhang, Q Lv, B Yu - Chinese Chemical Letters, 2022 - Elsevier
Graphene oxide (GO), as a metal-free and readily available carbocatalyst, has been
extensively applied in catalytic organic transformations. This minireview aims to give an …

Synthesis of 4-alkylated 1, 4-dihydropyridines: Fe (II)-mediated oxidative cascade cyclization reaction of cyclic ethers with enaminones

Y Sun, Z Liu, D Liu, M Zhang, L Chen… - The Journal of …, 2023 - ACS Publications
Syntheses of highly functionalized 4-alkylated 1, 4-dihydropyridines (1, 4-DHPs) from cyclic
ethers and enaminones via iron (II)-mediated oxidative free radical cascade C (sp3)–H bond …

Selectfluor facilitated bridging of indoles to bis (indolyl) methanes using methyl tert-butyl ether as a new methylene precursor

J Jin, Y Li, S Xiang, W Fan, S Guo… - Organic & Biomolecular …, 2021 - pubs.rsc.org
A novel, green and efficient method is developed for the synthesis of methylene bridged bis
(indolyl) methanes in good to excellent yields. The reaction employs methyl tert-butyl ether …

Graphene oxide-catalyzed trifluoromethylation of alkynes with quinoxalinones and Langlois' reagent

H Li, X Peng, L Nie, L Zhou, M Yang, F Li, J Hu, Z Yao… - RSC …, 2021 - pubs.rsc.org
The direct C–H trifluoromethylation of alkynes and quinoxalinones has been achieved using
a graphene oxide/Langlois' reagent system. This multi-component tandem reaction using …

Lewis acid-catalyzed double addition of indoles to ketones: synthesis of bis (indolyl) methanes with all-carbon quaternary centers

SO Lee, J Choi, S Kook, SY Lee - Organic & Biomolecular Chemistry, 2020 - pubs.rsc.org
We report herein a Lewis acid-catalyzed nucleophilic double-addition of indoles to ketones
under mild conditions. This process occurs with various ketones ranging from dialkyl …

Visible-light-induced, graphene oxide-promoted C3-chalcogenylation of indoles strategy under transition-metal-free conditions

Q Huang, X Peng, H Li, H He, L Liu - Molecules, 2022 - mdpi.com
An efficient and general method for the synthesis of 3-sulfenylindoles and 3-selenylindoles
employing visible-light irradiation with graphene oxide as a promoter at room temperature …

The direct C3 chalcogenylation of indolines using a graphene-oxide-promoted and visible-light-induced synergistic effect

C Liu, X Peng, D Hu, F Shi, P Huang, J Luo… - New Journal of …, 2020 - pubs.rsc.org
A new and efficient method for the C3–chalcogenylation of indolines, employing visible light
irradiation, and graphene oxide as a promoter, at room temperature has been achieved. The …

Recent Advance on the Synthesis of 3, 3'-Bisindolylmethane Derivatives under Transition-Metal-Free Catalytic Conditions

Z Zhenguo, L Xiaoxiao, Z Xinlong, Y Yalin… - Chinese Journal of …, 2021 - sioc-journal.cn
Bisindolylmethanes (3, 3'-BIMs) compounds are important indole alkyloads and their units
are widely found in various natural products, functional materials and synthetic …

Fe-mediated oxidative cascade [1+ 2+ 3]-cyclization/esterification reaction: synthesis of 4-alkylated 1, 4-dihydropyridines

Z Liu, Y Sun, M Zhang, L Chen, XB Chen… - Organic & Biomolecular …, 2023 - pubs.rsc.org
An Fe-mediated four-component reaction of enaminones, anhydrides and tetrahydrofuran
through a cascade [1+ 2+ 3]-cyclization/esterification process is presented. This protocol …