Mesokinetics as a tool bridging the microscopic-to-macroscopic transition to rationalize catalyst design

W Chen, G Qian, Y Wan, D Chen, X Zhou… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Heterogeneous catalysis is the workhorse of the chemical industry, and a
heterogeneous catalyst possesses numerous active sites working together to drive the …

Metal-organic framework-derived nanomaterials: Promising green catalysts for industrially relevant oxidation and hydrogenation

S Liu, Z Cheng, D Jia, H Gao, T Li, J Chen… - Nano Today, 2023 - Elsevier
Catalytic oxidation and hydrogenation reactions are fundamental and significant processes
in the modern-day chemical industry, necessary for the manufacture of key chemicals and …

Adsorption site regulation to guide atomic design of Ni–Ga catalysts for acetylene semi‐hydrogenation

Y Cao, H Zhang, S Ji, Z Sui, Z Jiang… - Angewandte Chemie …, 2020 - Wiley Online Library
Atomic regulation of metal catalysts has emerged as an intriguing yet challenging strategy to
boost product selectivity. Here, we report a density functional theory‐guided atomic design …

Understanding size-dependent hydrogenation of dimethyl oxalate to methyl glycolate over Ag catalysts

G Dong, Z Luo, Y Cao, S Zheng, J Zhou, W Li, X Zhou - Journal of Catalysis, 2021 - Elsevier
Ag catalysts are promising for the selective hydrogenation of dimethyl oxalate (DMO) to
methyl glycolate (MG), where the size of Ag nanoparticles strongly dominates their catalytic …

[HTML][HTML] Structural and kinetics understanding of support effects in Pd-catalyzed semi-hydrogenation of acetylene

Y Cao, X Ge, Y Li, R Si, Z Sui, J Zhou, X Duan, X Zhou - Engineering, 2021 - Elsevier
In this study, the support effects on the Pd-catalyzed semi-hydrogenation of acetylene have
been investigated from the structural and kinetic perspectives. According to the results of …

Mechanistic and atomic-level insights into semihydrogenation catalysis to light olefins

Y Li, K Yan, Y Cao, X Ge, X Zhou, W Yuan, D Chen… - ACS …, 2022 - ACS Publications
Semihydrogenations of alkynes and alkadienes to light olefins catalyzed by a
heterogeneous catalyst are widely applied in the chemical industry, but it remains …

Catalysis of semihydrogenation of acetylene to ethylene: Current trends, challenges, and outlook

TD Shittu, OB Ayodele - Frontiers of Chemical Science and Engineering, 2022 - Springer
Ethylene is an important feedstock for various industrial processes, particularly in the
polymer industry. Unfortunately, during naphtha cracking to produce ethylene, there are …

Al2O3 microrods supported Pd catalysts for semi-hydrogenation of acetylene: Acidic properties tuned reaction kinetics behaviors

Z Yang, Y Li, Y Cao, X Zhao, W Chen, J Zhang… - Chemical Engineering …, 2022 - Elsevier
The acidic properties of the support show remarkable effects on Pd-catalyzed reactions
including the semi-hydrogenation of acetylene. Herein, Al 2 O 3 microrods with distinct …

Tailoring electronic properties and kinetics behaviors of Pd/N‐CNTs catalysts for selective hydrogenation of acetylene

Y Cao, W Fu, Z Ren, Z Sui, J Zhou, J Luo… - AIChE …, 2020 - Wiley Online Library
Pd catalyzed selective hydrogenation of acetylene shows remarkable electronic effects. In
this work, a strategy is proposed to tailor the electronic properties of Pd nanoparticles by …

An experimental approach for controlling confinement effects at catalyst interfaces

TK Slot, N Riley, NR Shiju, JW Medlin… - Chemical …, 2020 - pubs.rsc.org
Catalysts are conventionally designed with a focus on enthalpic effects, manipulating the
Arrhenius activation energy. This approach ignores the possibility of designing materials to …