Ethylene oxychlorination on CeO2 provides ethylene dichloride (EDC) and the desired vinyl
chloride (VCM) in a single operation, in contrast to the traditional process that requires two …

The reactivity and regioselectivity of the electrophilic chlorination, nitration, and alkylation of
benzene derivatives were rationalized by comparing literature data for the partial rate factors …

A new cross-bridged cyclam chelator, CB-TE1K1P, was developed for copper-based
radiopharmaceuticals, and this chelator can be labelled with 64Cu under mild conditions in …

Template condensation of 3, 5-di-tert-butyl-2-hydroxybenzaldehyde S-
methylisothiosemicarbazone with pentane-2, 4-dione and triethyl orthoformate at elevated …

The tailoring reaction of the two adjacent nitrile ligands in cis-[PtCl2 (RCN) 2](R= Me, Et,
CH2Ph, Ph) and [Pt (tmeda)(EtCN) 2][SO3CF3] 2 (8·(OTf) 2; tmeda= N, N, N′, N …

The gas-and aqueous-phase acidities of a series of oxicams have been computed by
combining M05-2X/6-311+ G (3df, 2p) gas-phase free energies with solvation free energies …

Ni-catalyzed reductive cross-coupling reactions of electrophilic regents provide an important
method to form C–C bonds. The present study explored several single electron transfer …

Catalytic dinitrogen reduction with the Schrock complex is still hampered by low turn-over
numbers that are likely to result from a degradation of the chelate ligand. In this work, we …

Laser flash photolysis has been used to determine the bimolecular rate constants and the
spectral nature of the intermediates obtained by the reaction of sulfate radical anion (SO) …

Crystallographic, mutagenesis, kinetic, and computational studies on Rubisco over three
decades have revealed much about its catalytic mechanism and the role played by several …