Indolosesquiterpenoids are a growing class of natural products that exhibit a wide range of
biological activities. Here, we report the total syntheses of xiamycin A and oridamycins A and …

This review highlights the recent applications of titanocene (III) complexes in the field of
natural product synthesis from the seminal precedents to the development of modern …

Chiral amino acids (AAs), being the main “building” blocks of the living organisms, are also
an important class of organic compounds which broadly applied in synthetic chemistry …

In the last two decades, titanocene monochloride has been postulated as a monoelectronic
transfer reagent capable of catalyzing an important variety of chemical transformations. In …

The development of Green Chemistry inevitably involves the development of green
reagents. In this review, we highlight that Cp2TiCl is a reagent widely used in radical and …

A concise, protecting group-free total synthesis of (−)-fusarisetin A (1) was efficiently
achieved in nine steps from commercially available (S)-(−)-citronellal. The synthetic …

Terpene and terpenoid cyclizations are counted among the most complex chemical
reactions occurring in nature and contribute crucially to the tremendous structural diversity of …

The daphnezomine A‐type subfamily of Daphniphyllum alkaloids structurally features a
unique aza‐adamantane core skeleton and anticipates efficient strategies for completing …

Meroterpenes derived from dimethylorsellinic acid (DMOA) and farnesyl pyrophosphate
have attracted much biosynthetic attention, yet only recently have synthetic solutions to any …

By exploiting solvent and anion effects,[Cp2Ti]+ complexes for atom‐economical catalysis in
single‐electron steps were developed and applied for the first time. These complexes …