Combining the Power of TiIII‐Mediated Processes for Easy Access to Hydroxylated Polycyclic Terpenoids: Synthesis of Sesterstatin 1 and C–D Rings of …

T Jiménez, SP Morcillo… - … A European Journal, 2012 - Wiley Online Library
A straightforward access to polyhydroxylated terpenoids based on two key titanocene (III)‐
mediated reactions is presented: the “head‐to‐tail” Barbier‐type addition of prenyl chlorides …

SmI 2–H 2 O-mediated 5-exo/6-exo lactone radical cyclisation cascades

I Yalavac, SE Lyons, MR Webb… - Chemical …, 2014 - pubs.rsc.org
SmI 2 –H 2 O-mediated 5- exo /6- exo lactone radical cyclisation cascades - Chemical
Communications (RSC Publishing) DOI:10.1039/C4CC05404K Royal Society of Chemistry …

[HTML][HTML] Photoredox/Ti dual-catalyzed dehydroxylative ring-opening Giese reaction of cyclobutanone oximes

H Li, Y Li, W Yuan, A Qu, K Chen, Y Zhu - Green Synthesis and Catalysis, 2023 - Elsevier
A dehydroxylative ring-opening Giese reaction of cyclobutanone oximes enabled by
photoredox/Ti dual catalysis has been reported in this work. This protocol avoids the …

Radical-based epoxide opening by titanocenes

A Cangönül, M Behlendorf, A Gansäuer… - Inorganic …, 2013 - ACS Publications
The binding of 2, 2-diphenyloxirane to Cp2TiCl is studied on the electronic level by magnetic
resonance spectroscopy and quantum chemical calculations. The complexation of 2, 2 …

A new strategy for coupling amides or nitriles with diarylketones promoted by samarium metal under the catalysis of CuI

M Mi, C Liu, H Chen, Y Qi, Y Liu - Tetrahedron Letters, 2023 - Elsevier
Promoted by samarium metal, the novel condensation reaction of low activity α-H and
benzophones was realized under the catalysis of cuprous iodide under the mild conditions …

Toward the understanding of radical reactions: Experimental and computational studies of titanium (III) diamine bis (phenolate) complexes

S Barroso, F Madeira, MJ Calhorda… - Inorganic …, 2013 - ACS Publications
Radical reactions of titanium (III)[Ti (t Bu2O2NN′) Cl (S)](S= THF, 1; S= py, 2; t
Bu2O2NN′= Me2N (CH2) 2N (CH2-2-O-3, 5-t Bu2C6H2) 2) are described. Reactions with …

Structural diversity from the transannular cyclizations of natural germacrone and epoxy derivatives: A theoretical–experimental study

MC Perez Morales, JV Catalán… - … A European Journal, 2013 - Wiley Online Library
Abstract Treatment of germacrone (1) with different electrophiles, and of its epoxy derivatives
germacrone‐4, 5‐epoxide (2), germacrone‐1, 10‐epoxide (3) and isogermacrone‐4, 5 …

Diastereoselective synthesis of (±)-ambrox by titanium (III)-catalyzed radical tandem cyclization

A Rosales, LAR Foley, NM Padial, J Munoz-Bascon… - Synlett, 2016 - thieme-connect.com
Thieme E-Journals - Synlett / Full Text DE EN Home Products Journals Books Book Series
Service Library Service Help Contact Portal SYNLETT Full-text search Full-text search Author …

[HTML][HTML] Cp2TiCl/D2O/Mn, a formidable reagent for the deuteration of organic compounds

A Rosales, I Rodríguez-García - Beilstein Journal of Organic …, 2016 - beilstein-journals.org
Abstract Cp 2 TiCl/D 2 O/Mn is an efficient combination, sustainable and cheap reagent that
mediates the D-atom transfer from D 2 O to different functional groups and can contribute to …

Synthesis of labdane diterpenes galanal A and B from (+)-sclareolide

CNSSP Kumar, RJ Chein - Organic letters, 2014 - ACS Publications
Synthesis of Labdane Diterpenes Galanal A and B from (+)-Sclareolide | Organic Letters ACS
ACS Publications C&EN CAS Find my institution Log In Organic Letters ACS Publications. Most …