54 K Spin Transition Temperature Shift in a Fe6L4 Octahedral Cage Induced by Optimal Fitted Multiple Guests

F Yin, J Yang, LP Zhou, X Meng, CB Tian… - Journal of the …, 2024 - ACS Publications
Spin-crossover (SCO) coordination cages are at the forefront of research for their potential in
crafting next-generation molecular devices. However, due to the scarcity of SCO hosts and …

Anion-Mediated Allosteric Catalysis of [2+ 2] Photocycloaddition Based on a Flexible Metallo-Amine Cage for High Diastereoselectivity

YL Lu, YH Qin, SP Zheng, J Ruan, YH Huang… - ACS …, 2023 - ACS Publications
Anions can exert a notable influence on the solubility and folding of protein structures,
consequently altering their activity and stability due to the well-known Hofmeister effect …

Enantioselective [2+ 2] Cross-Photocycloaddition Enabled by a Chiral Cage Reactor via Multilevel-Selectivity Control

J Ruan, Z Li, C Yin, YL Lu, ZW Wei, P Hu, CY Su - ACS Catalysis, 2024 - ACS Publications
In the recently burgeoning field of asymmetric [2+ 2] photocycloaddition, a challenging
hurdle lies in achieving a multilevel control of chemo-, regio-, diastereo-, and …

Catalytic Enantioselective Cycloaddition Transformation of Tricyclic Arenes Enabled by a Dual-Role Chiral Cage-Reactor

J Chen, X Wu, S Huang, J Yang, YL Lu, Z Jiao… - ACS …, 2024 - ACS Publications
An enzyme mimic catalytic system was established by employing a chiral metal–organic
cage as the supramolecular reactor, and asymmetric dearomative Diels–Alder (D–A) …

Dynamic Stereochemistry of M8Pd6 Supramolecular Cages Based on Metal‐Center Lability for Differential Chiral Induction, Resolution, and Recognition

YH Huang, YL Lu, XD Zhang, CH Liu… - Angewandte …, 2024 - Wiley Online Library
A series of isostructural supramolecular cages with a rhombic dodecahedron shape have
been assembled with distinct metal‐coordination lability (M8Pd6‐MOC‐16, M= Ru2+, Fe2+ …

Strain‐Induced Heteromorphosis Multi‐Cavity Cages: Tension‐Driven Self‐Expansion Strategy for Controllable Enhancement of Complexity in Supramolecular …

J Wang, Z Jiang, JF Yin, H Zhao, Q Dong… - Angewandte Chemie …, 2024 - Wiley Online Library
Coordinative supramolecular cages with adjustable cavities have found extensive
applications in various fields, but the cavity modification strategies for multi‐functional …