Enantiomers, where chirality arises from restricted rotation around a single bond, are
atropisomers. Due to the unique nature of the origins of their chirality, synthetic strategies to …

Axially chiral architectures exist widely in natural products, biologically relevant molecules,
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …

An additive‐and external oxidant‐free reaction of cyclopropanols, DABCO⋅(SO2) 2 and
diaryliodonium salts in aqueous phase is described. This reaction proceeds under mild …

We herein introduce biarylhemiboronic esters as a new type of bridged biaryl reagent for
asymmetric synthesis of axially chiral biaryl structures, and the palladium-catalyzed …

We report an organocatalyst that combines a triazolium N-heterocyclic carbene (NHC) with a
squaramide as a hydrogen-bonding donor (HBD), which can effectively catalyze the …

Disclosed here is NHC-catalyzed direct intermolecular trapping of the ketone oxygen atom
with the acyl azolium intermediate. The overall reaction is a dynamic kinetic resolution …

The development of catalytic asymmetric reaction with water as the reactant is challenging
due to the reactivity‐and stereoselectivity‐control issues resulted from the low nucleophilicity …

The catalytic atroposelective synthesis of axially chiral heterobiaryls was first developed
through the direct one-step dynamic kinetic condensation reaction with the simple …

The development of efficient processes for the preparation of structurally diverse axially
chiral biaryls has been an important goal in synthetic organic chemistry and asymmetric …

Axially chiral heterobiaryl frameworks are privileged structures in many natural products,
pharmaceutically active molecules, and chiral ligands. Therefore, a variety of approaches for …