Exsolution of Ru Nanoparticles on BaCe0.9Y0.1O3‐δ Modifying Geometry and Electronic Structure of Ru for Ammonia Synthesis Reaction Under Mild Conditions

H Kim, A Jan, DH Kwon, HI Ji, KJ Yoon, JH Lee, Y Jun… - Small, 2023 - Wiley Online Library
Green ammonia is an efficient, carbon‐free energy carrier and storage medium. The
ammonia synthesis using green hydrogen requires an active catalyst that operates under …

Influence of Reaction Conditions and Promoting Role of Ammonia Produced at Higher Temperature Conditions in Its Synthesis Process over Cs‐Ru/MgO Catalyst

R Javaid, H Matsumoto, T Nanba - ChemistrySelect, 2019 - Wiley Online Library
Abstract Cs promoted Ru/MgO catalyst was prepared by an impregnation method using Ru
(NO3) 3 and Cs (NO3) 2 as precursor compounds. The activity measurements for ammonia …

Breaking the scaling relations for efficient N2-to-NH3 conversion by a bowl active site design: Insight from LaRuSi and isostructural electrides

YF Jiang, JC Liu, CQ Xu, J Li, H Xiao - Chinese Journal of Catalysis, 2022 - Elsevier
The design of optimal heterogeneous catalysts for N 2-to-NH 3 conversion is often dictated
by the scaling relations, which result in a volcano curve that poses a limit on the catalytic …

Efficient ammonia synthesis over phase-separated nickel-based intermetallic catalysts

TN Ye, Y Lu, Y Kobayashi, J Li, SW Park… - The Journal of …, 2020 - ACS Publications
Ammonia is one of the most important industrial intermediates due to the mass-demand for
the production of various chemicals. Since the development of the Haber–Bosch process …

The current methods of ammonia synthesis by Haber-Bosch process

MR Moghadam, A Bazmandegan-Shamili… - Progresses in Ammonia …, 2024 - Elsevier
Abstract The Haber-Bosch process for ammonia synthesis is one of the most important
human inventions that dramatically increased the world population by increasing the …

Deciphering the nature of Ru sites in reductively exsolved oxides with electronic and geometric metal–support interactions

MA Naeem, DB Burueva, PM Abdala… - The Journal of …, 2020 - ACS Publications
The reductive exsolution of metallic Ru from fluorite-type solid solutions Ln2Ru0. 2Ce1. 8O7
(Ln= Sm, Nd, La) leads to materials with metal–support interactions that influence the …

BaCu, a Two-Dimensional Electride with Cu Anions

B Wan, Y Yuan, L Zheng, Y Xu, S Zhao… - Journal of the …, 2024 - ACS Publications
The electron-rich characteristic and low work function endow electrides with excellent
performance in (opto) electronics and catalytic applications; these two features are closely …

A View on Formation Gap in Transition Metal Hydrides and Its Collapse

H Mizoguchi, SW Park, H Hosono - Journal of the American …, 2021 - ACS Publications
Late transition metals (LTMs) do not form hydrides under conventional experimental
conditions except for palladium (Pd). The incorporation of a small amount of metal with low …

Porous intermetallic Ni 2 XAl (X= Ti or Zr) nanoparticles prepared from oxide precursors

Y Kobayashi, S Tada, R Kikuchi - Nanoscale Advances, 2021 - pubs.rsc.org
Porous intermetallic Ni2XAl (X= Ti or Zr) nanoparticles with small crystallite sizes (24–34
nm) and high Brunauer–Emmett–Teller (BET) surface areas (10–71 m2 g− 1) were prepared …

Barium-promoted ruthenium catalysts on yittria-stabilized zirconia supports for ammonia synthesis

Z Zhang, C Karakaya, RJ Kee, JD Way… - ACS Sustainable …, 2019 - ACS Publications
The cost-effective, small-scale, distributed synthesis of ammonia depends on effective
catalysts and processes that operate under modest elevated pressure (ie, p< 20 bar) …