Hypervalent iodine compounds as environmentally friendly and relatively inexpensive
reagents have properties similar to transition metals. They are employed as alternatives to …

Hypervalent aryliodoumiums are intensively investigated as arylating agents. They are
excellent surrogates to aryl halides, and moreover they exhibit better reactivity, which allows …

Conspectus Asymmetric electrophilic reactions provide an ideal method for the construction
of chiral molecules by incorporating one or more functional groups into the parent substrates …

Structural engineering permits the introduction of chirality into organic–inorganic hybrid
metal halides (HMHs), which creates a promising and exclusive material for applications in …

The rhodium-catalyzed enantioselective C–H iodination of 1-aryl isoquinolines under mild
conditions is disclosed. Direct C–H iodination of 1-aryl isoquinolines with N-iodosuccinimide …

Catalyst design has traditionally focused on rigid structural elements to prevent
conformational flexibility. Ishihara's elegant design of conformationally flexible C 2 …

Catalytic enantioselective synthesis of chiral helicenes and helicenoids has emerged as an
important area of research. In the efforts toward efficient and enantioselective synthesis of …

A remarkable growth in hypervalent iodine‐mediated oxidative transformations as
stoichiometric reagents as well as catalysts has been well‐documented due to their …

Fluorinated small molecules are prevalent across the functional small-molecule spectrum,
but the scarcity of naturally occurring sources creates an opportunity for creative endeavour …

Partially saturated, fluorine-containing rings are ubiquitous across the drug discovery
spectrum. This capitalises upon the biological significance of the native structure and the …