Synthesis and applications of anisotropic nanoparticles with precisely defined dimensions

AK Pearce, TR Wilks, MC Arno… - Nature Reviews Chemistry, 2021 - nature.com
Shape and size play powerful roles in determining the properties of a material; controlling
these aspects with precision is therefore an important, fundamental goal of the chemical …

Porphyrin-based supramolecular polymers

H Lee, H Park, DY Ryu, WD Jang - Chemical Society Reviews, 2023 - pubs.rsc.org
Porphyrin derivatives are ubiquitous in bio-organisms and are associated with proteins that
play important biological roles, such as oxygen transport, photosynthesis, and catalysis …

Mutual monomer orientation to bias the supramolecular polymerization of [6] helicenes and the resulting circularly polarized light and spin filtering properties

R Rodríguez, C Naranjo, A Kumar… - Journal of the …, 2022 - ACS Publications
We report on the synthesis and self-assembly of 2, 15-and 4, 13-disubstituted carbo [6]
helicenes 1 and 2 bearing 3, 4, 5-tridodecyloxybenzamide groups. The self-assembly of …

Multistep, site-selective noncovalent synthesis of two-dimensional block supramolecular polymers

N Sasaki, J Kikkawa, Y Ishii, T Uchihashi, H Imamura… - Nature Chemistry, 2023 - nature.com
Although the principles of noncovalent bonding are well understood and form the basis for
the syntheses of many intricate supramolecular structures, supramolecular noncovalent …

Controlled noncovalent synthesis of secondary supramolecular polymers

S Sarkar, R Laishram, D Deb… - Journal of the American …, 2023 - ACS Publications
Dynamic supramolecular polymers, with their functional similarities to classical covalent
polymers and their adaptive and self-repairing nature reminiscent of biological assemblies …

Pathway complexity in supramolecular copolymerization and blocky star copolymers by a hetero-seeding effect

P Khanra, AK Singh, L Roy, A Das - Journal of the American …, 2023 - ACS Publications
This study unravels the intricate kinetic and thermodynamic pathways involved in the
supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (NMI) …

Secondary nucleation-triggered physical cross-links and tunable stiffness in seeded supramolecular hydrogels

R Laishram, S Sarkar, I Seth, N Khatun… - Journal of the …, 2022 - ACS Publications
Mechanistic understanding and the control of molecular self-assembly at all hierarchical
levels remain grand challenges in supramolecular chemistry. Functional realization of …

Stereoselective primary and secondary nucleation events in multicomponent seeded supramolecular polymerization

S Sarkar, A Sarkar, A Som, SS Agasti… - Journal of the American …, 2021 - ACS Publications
Bioinspired, kinetically controlled seeded growth has been recently shown to provide length,
dispersity, and sequence control on the primary structure of dynamic supramolecular …

Polymorphism in Squaraine Dye Aggregates by Self‐Assembly Pathway Differentiation: Panchromatic Tubular Dye Nanorods versus J‐Aggregate Nanosheets

CA Shen, D Bialas, M Hecht, V Stepanenko… - Angewandte …, 2021 - Wiley Online Library
A bis (squaraine) dye equipped with alkyl and oligoethyleneglycol chains was synthesized
by connecting two dicyanomethylene substituted squaraine dyes with a phenylene spacer …

Tricomponent supramolecular multiblock copolymers with tunable composition via sequential seeded growth

A Sarkar, R Sasmal, A Das… - Angewandte Chemie …, 2021 - Wiley Online Library
Synthesis of supramolecular block co‐polymers (BCP) with small monomers and predictive
sequence requires elegant molecular design and synthetic strategies. Herein we report the …