Cleavage of carbon–carbon bonds by radical reactions
P Sivaguru, Z Wang, G Zanoni, X Bi - Chemical Society Reviews, 2019 - pubs.rsc.org
In recent years, radical C–C bond cleavage reactions have been increasingly understood
and used to perform transformations that complement traditional ionic processes. However …
and used to perform transformations that complement traditional ionic processes. However …
Recent advances in the direct functionalization of quinoxalin-2 (1 H)-ones
Q Ke, G Yan, J Yu, X Wu - Organic & Biomolecular Chemistry, 2019 - pubs.rsc.org
The direct C3-functionalization of quinoxalin-2 (1H)-ones via C–H bond activation has
recently attracted considerable attention, due to their diverse biological activities and …
recently attracted considerable attention, due to their diverse biological activities and …
Uses of K2S2O8 in Metal-Catalyzed and Metal-Free Oxidative Transformations
Carbon–carbon/carbon–heteroatom bond formation via oxidative transformations is a
heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has …
heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has …
Visible light photocatalytic phosphorylation of heteroatom nucleophiles triggered by phosphorus-centered radical cations
Y Huang, J Tang, X Zhao, Y Huo, Y Gao, X Li… - Green …, 2023 - pubs.rsc.org
The development of P (O)–heteroatom bond-forming reactions is of vital importance.
However, previous methods all have their own limitations and drawbacks. Herein, we …
However, previous methods all have their own limitations and drawbacks. Herein, we …
Mn(OAc)3-Promoted Oxidative Csp3–P Bond Formation through Csp2–Csp2 and P–H Bond Cleavage: Access to β-Ketophosphonates
P Zhou, B Hu, L Li, K Rao, J Yang… - The Journal of Organic …, 2017 - ACS Publications
The Mn (OAc) 3-promoted oxidative phosphonylation of N, N-dimethylenaminones with H-
phosphonates, involving a chemo-and regioselective Csp2–Csp2 bond cleavage and Csp3 …
phosphonates, involving a chemo-and regioselective Csp2–Csp2 bond cleavage and Csp3 …
[PDF][PDF] Electrocatalytic C–H phosphorylation through nickel (III/IV/II) catalysis
C–H phosphorylation was achieved by Earth-abundant nickel catalysts with waste-free
electricity as the redox surrogate. The robust nickela-electrooxidative C–H activation of …
electricity as the redox surrogate. The robust nickela-electrooxidative C–H activation of …
A phosphoryl radical-initiated Atherton–Todd-type reaction under open air
Y Ou, Y Huang, Z He, G Yu, Y Huo, X Li… - Chemical …, 2020 - pubs.rsc.org
A phosphoryl radical-initiated Atherton–Todd-type reaction using air as the radical initiator
and CHCl3 as the halogenating reagent for the phosphorylation of alcohols, phenols, and …
and CHCl3 as the halogenating reagent for the phosphorylation of alcohols, phenols, and …
Simple silver (i)-salt catalyzed selective hydroboration of isocyanates, pyridines, and quinolines
AgSbF6 has been established as an effective catalyst for the hydroboration of structurally
and electronically diverse isocyanates under ligand-and solvent-free conditions which …
and electronically diverse isocyanates under ligand-and solvent-free conditions which …
Recent Advances in Silver‐Catalyzed Transformations of Electronically Unbiased Alkenes and Alkynes
M Li, W Wu, H Jiang - ChemCatChem, 2020 - Wiley Online Library
Silver, as one of the most ancient coinage metals, has attracted a plethora of attention from
chemists in recent years due to the easy availability, high catalytic efficiency and multiple …
chemists in recent years due to the easy availability, high catalytic efficiency and multiple …
Ruthenium (ii)-catalyzed chemoselective deacylative annulation of 1, 3-diones with sulfoxonium ylides via C–C bond activation
S Wen, W Lv, D Ba, J Liu, G Cheng - Chemical Science, 2019 - pubs.rsc.org
The first successful example of deacylative annulation of 1, 3-diones with sulfoxonium ylides
was achieved through Ru (II)-catalyzed C–C bond activation. The excellent chemoselectivity …
was achieved through Ru (II)-catalyzed C–C bond activation. The excellent chemoselectivity …