Heteroatoms as well as heterocyclic scaffolds are frequently present as the common cores in
a plethora of active pharmaceuticals natural products. Statistically, more than 85% of all …

Suzuki‐Miyaura Coupling Reaction (SMCR) has been extensively used in the total synthesis
of natural products. We underscored these achievements in a report published in …

The first examples of enantioselective doubly decarboxylative cross coupling are disclosed.
Malonate half amides are smoothly coupled to a variety of primary carboxylic acids after …

Carbonyl groups that bear an α stereocenter are commonly found in bioactive compounds,
and intense effort has therefore been dedicated to the pursuit of stereoselective methods for …

The chemo-, regio-, diastereo-, and enantioselective 1, 2-oxyamination of alkenes using
selenium (II/IV) catalysis with a chiral diselenide catalyst is reported. This method uses N …

The Knoevenagel condensation reaction is a prominent organic reaction commonly being
utilized in the total synthesis of natural and biologically potent products as a vital and …

This review article describes the use of some of the most popular chiral auxiliaries in the
asymmetric synthesis of biologically active compounds. Chiral auxiliaries derived from …

Heterocyclic compounds are among the most prestigious and valuable chemical molecules
with diverse and magnificent applications in various sciences. Due to the remarkable and …

Over the years, Friedel–Crafts (FC) reactions have been acknowledged as the most useful
and powerful synthetic tools for the construction of a special kind of carbon–carbon bond …

Vinyl boron ate complexes of enantioenriched secondary alkyl pinacolboronic esters
undergo stereospecific radical‐induced 1, 2‐migration in radical polar crossover reactions …