Bimetallic catalysis has emerged as an efficient strategy for the development of new
chemical reactions. Importantly, this strategy also provides a simple and powerful platform …

Hydrofunctionalisation and difunctionalisation of dienes, allenes, and alkynes are widely
utilized in the synthesis of valuable allylic compounds. In the past decades, asymmetric …

In contrast to the widely explored methods for the asymmetric synthesis of molecules
bearing a single stereocenter or adjacent stereocenters, the concurrent construction of 1, 3 …

Comprehensive computational studies were carried out to explore the mechanisms of
enantioselective Cu/Pd and stereodivergent Cu/Ir dual-catalytic syntheses of α, α …

Herein we describe a protocol for the unprecedented stereodivergent synthesis of tertiary
fluoride-tethered allenes bearing a stereogenic center and stereogenic axis via Cu/Pd …

The development of efficient and straightforward methods for obtaining all optically active
isomers of structurally rigid spirocycles from readily available starting materials is of great …

This Perspective presents an overview of catalytic enantioselective transformations that
allow convenient access to all stereoisomers of a given product with multiple stereogenic …

An unprecedented hydroalkylation of racemic allylic alcohols and racemic ketimine esters
enabled by Cu/Ru relay catalysis has been developed via merging the ruthenium‐catalyzed …

We describe a fully stereodivergent synthesis of a range of α, α-disubstituted α-amino acids
via an Ir/Cu-catalyzed α-allylation of readily available imine esters. The introduction of a Cu …

A one-pot rhodium-catalyzed C–H functionalization/organocatalyzed oxa-Michael addition
cascade reaction has been developed. This methodology enables the stereodivergent …