Increasing the Magnetic Blocking Temperature of Single‐Molecule Magnets

V Vieru, S Gómez‐Coca, E Ruiz… - Angewandte …, 2024 - Wiley Online Library
The synthesis of single‐molecule magnets (SMMs), magnetic complexes capable of
retaining magnetization blocking for a long time at elevated temperatures, has been a major …

A Paradigm Shift from 2D to 3D: Surface Supramolecular Assemblies and Their Electronic Properties Explored by Scanning Tunneling Microscopy and Spectroscopy

R Xie, Y Hu, SL Lee - Small, 2023 - Wiley Online Library
Exploring supramolecular architectures at surfaces plays an increasingly important role in
contemporary science, especially for molecular electronics. A paradigm of research interest …

[HTML][HTML] A pillar [5] arene noncovalent assembly boosts a full-color lanthanide supramolecular light switch

WL Zhou, XY Dai, W Lin, Y Chen, Y Liu - Chemical Science, 2023 - pubs.rsc.org
A photo-responsive full-color lanthanide supramolecular switch was constructed from a
synthetic 2, 6-pyridine dicarboxylic acid (DPA)-modified pillar [5] arene (H) complexing with …

KNN-based optical temperature sensing ceramics integrating negative thermal quenching and photochromic self-recovery behavior

Y Chen, F Yu, S Zhong, L Deng, X Wu, C Lin… - Journal of …, 2023 - Elsevier
Abstract Rare-earth ion (RE 3+) doped materials with upconversion luminescence and
photochromic (PC) effect have received widespread attention, but thermal quenching (TQ) at …

Tetraquinoxalinoporphyrazine–π-extended NIR-absorbing photosensitizer with improved photostability

AV Yagodin, IA Mikheev, DA Bunin… - Dyes and …, 2023 - Elsevier
A novel ionogenic water-soluble zinc complex with π-extended ligand–
tetraquinoxalinoporphyrazine bearing eight benzoate groups–ZnQPz (COONa) 8 was …

Unexpected Supramolecular-Induced Redox Switching in Sandwich Gd Bisphthalocyaninate

AA Sinelshchikova, LA Lapkina, VE Larchenko… - Inorganic …, 2024 - ACS Publications
The redox state of the phthalocyanine in sandwich lanthanide complexes is crucial for their
applications. In this work, we demonstrate that the cation-induced supramolecular assembly …

Solvation-Induced Conformational Switching of Trisphthalocyanates for Control of Their Magnetic Properties

AG Martynov, AA Sinelshchikova… - Inorganic …, 2023 - ACS Publications
Stabilization of different conformers of sandwich phthalocyaninates by changing the
solvation environment has been demonstrated with the examples of new heteroleptic yttrium …

[HTML][HTML] Redox-Triggered Switching of Conformational State in Triple-Decker Lanthanide Phthalocyaninates

AG Martynov, MA Polovkova, YG Gorbunova… - Molecules, 2022 - mdpi.com
Double-and triple-decker lanthanide phthalocyaninates exhibit unique physical-chemical
properties, particularly single-molecule magnetism. Among other factors, the magnetic …

Exploration of Intramolecular Interactions and Single-Molecule Magnetic Behaviors in MIII4LnIII2 (M = Fe, Ga; Ln = Dy, Y) Complexes

H Wang, S Liu, L Wei, G Deng, H Zhu… - Crystal Growth & …, 2023 - ACS Publications
Three hexanuclear heterometallic complexes, namely,[MIII4LnIII2 (μ3-OH) 2 (mdea) 4
(C6H5CO2) 6 (N3) 2]· H2O [M= Fe, Ln= Y (1); M= Ga, Ln= Dy (2); and M= Fe, Ln= Dy (3) …

Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets

K Bernot - European Journal of Inorganic Chemistry, 2023 - Wiley Online Library
The number of scientific articles that need to be considered to cover a research topic is ever‐
increasing and quite difficult for a newcomer to assimilate. This is particularly true in dynamic …