Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Molecular magnetism, though distinctly a field within chemistry, encompasses much more
than synthesis and has strong links with other disciplines across the physical sciences …

Here, we report the synthesis of two new sets of dibismuth-bridged rare earth molecules.
The first series contains a bridging diamagnetic Bi22–anion,(Cp* 2RE) 2 (μ-η2: η2-Bi2), 1 …

Single‐molecule magnets (SMMs) are at the forefront of new technological advances in
quantum information processing and spintronics. Despite the recent impressive …

Increasing the operating temperatures of single-molecule magnets—molecules that can
retain magnetic polarization in the absence of an applied field—has potential implications …

A porous hydrogen-bonded organic framework (HOF) responsive to acid was constructed
from a hexaazatrinaphthylene derivative with carboxyphenyl groups (CPHATN). Precise …

Systematic analysis of related compounds is crucial to the design of single-molecule
magnets with improved properties, yet such studies on multinuclear lanthanide complexes …

Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

In the field of molecular magnetism, the lanthanide–radical (Ln–Rad) method has become
one of the most appealing tactics for introducing strong magnetic interactions and has …

Inducing magnetic coupling between 4f elements is an ongoing challenge. To overcome this
formidable difficulty, we incorporate highly delocalized tetrazinyl radicals, which strongly …