Microscopic theory of heterogeneity and nonexponential relaxations in supercooled liquids

X Xia, PG Wolynes - Physical Review Letters, 2001 - APS
Recent experiments show that supercooled liquids around the glass transition temperature
are “dynamically heterogeneous”[H. Sillescu, J. Non-Cryst. Solids 243, 81 (1999)]. Such …

Colloquium: Random first order transition theory concepts in biology and physics

TR Kirkpatrick, D Thirumalai - Reviews of Modern Physics, 2015 - APS
The routine transformation of a liquid, as it is rapidly cooled, resulting in glass formation, is
remarkably complex. A theoretical explanation of the dynamics associated with this process …

Stochastic model of slow dynamics in supercooled liquids and dense colloidal suspensions

K Kawasaki - Physica A: Statistical Mechanics and its Applications, 1994 - Elsevier
We propose a stochastic model equation for the density variable which is intended for slow
dynamics occurring in supercooled liquids and dense colloidal suspensions near glass …

Colloidal hard spheres: Triumphs, challenges and mysteries

CP Royall, P Charbonneau, M Dijkstra, J Russo… - arXiv preprint arXiv …, 2023 - arxiv.org
The simplicity of hard spheres as a model system is deceptive. Although the particles
interact solely through volume exclusion, that nevertheless suffices for a wealth of static and …

On the surface of glasses

JD Stevenson, PG Wolynes - The Journal of chemical physics, 2008 - pubs.aip.org
Dynamics near the surface of glasses is generally much faster than in the bulk. Neglecting
static perturbations of structure at the surface, we use random first order transition (RFOT) …

The aperiodic crystal picture and free energy barriers in glasses

RW Hall, PG Wolynes - The Journal of chemical physics, 1987 - pubs.aip.org
The aperiodic crystal picture associates the glass transition with freezing into a nonperiodic
structure. Dynamics in the glassy state involves activated jumps between different aperiodic …

Order in metallic glasses and icosahedral crystals

S Sachdev, DR Nelson - Physical Review B, 1985 - APS
The relationship between short-range icosahedral order in metallic glasses and long-range
order in icosahedral crystals is explored. Metallic-glass structure factors are assumed to …

A density functional theory for polymers: Application to hard chain–hard sphere mixtures in slitlike pores

CE Woodward - The Journal of chemical physics, 1991 - pubs.aip.org
A density functional theory for polymer fluids is derived. The form of the theory is identical to
a continuum self-consistent-field theory but we show that with the correct" mean field," the …

Free-energy model for the inhomogeneous hard-sphere fluid in D dimensions: Structure factors for the hard-disk (D=2) mixtures in simple explicit form

Y Rosenfeld - Physical review A, 1990 - APS
A free-energy model for the inhomogeneous hard-sphere fluid mixture was derived recently
[Phys. Rev. Lett. 63, 980 (1989)], which is based on the fundamental geometric measures of …

Derivation of a microscopic theory of barriers and activated hopping transport in glassy liquids and suspensions

KS Schweizer - The Journal of chemical physics, 2005 - pubs.aip.org
A recently proposed microscopic activated barrier hopping theory [KS Schweizer and EJ
Saltzman, J. Chem. Phys. 119, 1181 (2003)] of slow single-particle dynamics in glassy …