Barrier softening near the onset of nonactivated transport in supercooled liquids: Implications for establishing detailed connection between thermodynamic and kinetic …

V Lubchenko, PG Wolynes - The Journal of chemical physics, 2003 - pubs.aip.org
A unified picture of the dynamics of supercooled liquids has emerged based on a theory of
random first-order transitions RFOTs. 1–3 The mean field approaches to structural glasses …

Theory of dynamic barriers, activated hopping, and the glass transition in polymer melts

KS Schweizer, EJ Saltzman - The Journal of chemical physics, 2004 - pubs.aip.org
A statistical mechanical theory of collective dynamic barriers, slow segmental relaxation, and
the glass transition of polymer melts is developed by combining, and in some aspects …

Importance of many-body orientational correlations in the physical description of liquids

H Tanaka - Faraday discussions, 2013 - pubs.rsc.org
Liquids are often assumed to be homogeneous and isotropic at any lengthscale and
translationally invariant. The standard liquid-state theory is constructed on the basis of this …

Theory of the structural glass transition: A pedagogical review

V Lubchenko - Advances in Physics, 2015 - Taylor & Francis
The random first-order transition theory of the structural glass transition is reviewed in a
pedagogical fashion. The rigidity that emerges in crystals and glassy liquids is of the same …

Free‐energy model for the inhomogeneous hard‐sphere fluid mixture: triplet and higher‐order direct correlation functions in dense fluids

Y Rosenfeld, D Levesque, JJ Weis - The Journal of chemical physics, 1990 - pubs.aip.org
Extensive Monte Carlo simulation results for the pair and triplet direct correlation functions of
the one‐component, hard‐sphere system near freezing are presented. These results are in …

Perturbation theories for the thermodynamic properties of fluids and solids

JR Solana - 2013 - books.google.com
This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids,
provides a comprehensive review of current perturbation theories—as well as integral …

Dynamical heterogeneity of the glassy state

A Wisitsorasak, PG Wolynes - The Journal of Physical Chemistry …, 2014 - ACS Publications
We compare dynamical heterogeneities in equilibrated supercooled liquids and in the
nonequilibrium glassy state within the framework of the random first order transition theory …

Thermodynamic− Kinetic Correlations in Supercooled Liquids: A Critical Survey of Experimental Data and Predictions of the Random First-Order Transition Theory of …

JD Stevenson, PG Wolynes - The Journal of Physical Chemistry B, 2005 - ACS Publications
Thermodynamics and kinetics are thought to be linked in glass transitions. The quantitative
predictions of α-relaxation activation barriers provided by the theory of glasses based on …

Derivation of coarse grained models for multiscale simulation of liquid crystalline phase transitions

B Mukherjee, L Delle Site, K Kremer… - The Journal of Physical …, 2012 - ACS Publications
We present a systematic derivation of a coarse grained (CG) model for molecular dynamics
(MD) simulations of a liquid crystalline (LC) compound containing an azobenzene mesogen …

Two-order-parameter model of the liquid–glass transition. I. Relation between glass transition and crystallization

H Tanaka - Journal of non-crystalline solids, 2005 - Elsevier
Recently we proposed a two-order-parameter model of liquid to understand the liquid–glass
transition, liquid–liquid transition, and anomalies of water-type liquids in a unified manner …