Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

[HTML][HTML] Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Ultrahard magnetism from mixed-valence dilanthanide complexes with metal-metal bonding

CA Gould, KR McClain, D Reta, JGC Kragskow… - Science, 2022 - science.org
Metal-metal bonding interactions can engender outstanding magnetic properties in bulk
materials and molecules, and examples abound for the transition metals. Extending this …

The OpenMolcas Web: A Community-Driven Approach to Advancing Computational Chemistry

G Li Manni, I Fdez. Galván, A Alavi… - Journal of chemical …, 2023 - ACS Publications
The developments of the open-source OpenMolcas chemistry software environment since
spring 2020 are described, with a focus on novel functionalities accessible in the stable …

Strong axiality in a dysprosium (III) bis (borolide) complex leads to magnetic blocking at 65 K

AH Vincent, YL Whyatt, NF Chilton… - Journal of the American …, 2023 - ACS Publications
Substituted dysprosocenium complexes of the type [Dy (Cp R) 2]+ exhibit slow magnetic
relaxation at cryogenic temperatures and have emerged as top-performing single-molecule …

Understanding the unceasing evolution of Co (II) based single-ion magnets

PK Sahu, R Kharel, S Shome, S Goswami… - Coordination Chemistry …, 2023 - Elsevier
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

[HTML][HTML] Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

Emerging trends on designing high-performance dysprosium (III) single-molecule magnets

TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

Lanthanide single-molecule magnets with high anisotropy barrier: where to from here?

Z Zhu, J Tang - National Science Review, 2022 - academic.oup.com
Lanthanide single-molecule magnets with high anisotropy barrier: where to from here? |
National Science Review | Oxford Academic Skip to Main Content Advertisement Oxford …

Computational design of magnetic molecules and their environment using quantum chemistry, machine learning and multiscale simulations

A Lunghi, S Sanvito - Nature Reviews Chemistry, 2022 - nature.com
Having served as a playground for fundamental studies on the physics of d and f electrons
for almost a century, magnetic molecules are now becoming increasingly important for …