Conspectus Transition metal complexes featuring an M═ NR bond have received great
attention as critical intermediates in the synthesis of nitrogen-containing compounds. In …

Actual problems of development of catalysts for hydrogenation of heterocyclic compounds
by hydrogen are summarized and discussed. The scope of review covers composites of …

Abstract Owing to their distinctive 1, 3‐dipolar structure, the catalytic asymmetric
hydrogenation of nitrones to hydroxylamines has been a formidable and longstanding …

Developing a general, highly efficient, and enantioselective catalytic method for the
synthesis of chiral alcohols is still a formidable challenge. We report in this article the …

Asymmetric photocatalysis consists of the synergistic effect of photocatalysis and
organocatalysis, in which the photoelectrons in photocatalysts catalyze substrates to …

An enantioselective isothiourea-catalysed [2+ 2] cycloaddition of C (1)-ammonium enolates
with pyrazol-4, 5-diones is used to construct spirocyclic β-lactones in good yields, excellent …

Stereoselective hydrogenation of tetrasubstituted olefins is an attractive method to access
compounds with two contiguous stereocenters. However, homogeneous catalysts for …

The development of new pharmaceutical compounds is challenging because most of them
are based on enantiopure chiral molecules, which exhibit unique properties for therapy …

Olefination of carbonyl compounds is a typical strategy for the synthesis of olefins. Herein,
we reported a rhodium‐catalyzed cross‐coupling reaction of ketones with arylboroxines for …

Machine learning driven Computer Aided Synthesis Planning (CASP) tools have become
important tools for idea generation in the design of complex molecule synthesis but do not …