2D Covalent Organic Framework Membranes for Liquid‐Phase Molecular Separations: State of the Field, Common Pitfalls, and Future Opportunities

DW Burke, Z Jiang, AG Livingston… - Advanced …, 2024 - Wiley Online Library
Abstract 2D covalent organic frameworks (2D COFs) are attractive candidates for next‐
generation membranes due to their robust linkages and uniform, tunable pores. Many …

The order–disorder conundrum: a trade-off between crystalline and amorphous porous organic polymers for task-specific applications

A Giri, Y Khakre, G Shreeraj, TK Dutta… - Journal of Materials …, 2022 - pubs.rsc.org
Porous organic polymers (POPs) have received increasing attention due to their properties,
such as permanent porosity with tunable pore size, robust structure, high surface area, and …

Single-crystalline imine-linked two-dimensional covalent organic frameworks separate benzene and cyclohexane efficiently

A Natraj, W Ji, J Xin, I Castano, DW Burke… - Journal of the …, 2022 - ACS Publications
Two-dimensional (2D) covalent organic frameworks (COFs) are composed of structurally
precise, permanently porous, layered macromolecular sheets, which are traditionally …

Three-dimensional covalent organic frameworks with pto and mhq-z topologies based on Tri-and tetratopic linkers

D Zhu, Y Zhu, Y Chen, Q Yan, H Wu, CY Liu… - Nature …, 2023 - nature.com
Abstract Three-dimensional (3D) covalent organic frameworks (COFs) possess higher
surface areas, more abundant pore channels, and lower density compared to their two …

Exceptionally high charge mobility in phthalocyanine-based poly (benzimidazobenzophenanthroline)-ladder-type two-dimensional conjugated polymers

M Wang, S Fu, P Petkov, Y Fu, Z Zhang, Y Liu, J Ma… - Nature Materials, 2023 - nature.com
Two-dimensional conjugated polymers (2DCPs), composed of multiple strands of linear
conjugated polymers with extended in-plane π-conjugation, are emerging crystalline …

Green and scalable synthesis of atomic-thin crystalline two-dimensional triazine polymers with ultrahigh photocatalytic properties

C Wang, P Lyu, Z Chen, Y Xu - Journal of the American Chemical …, 2023 - ACS Publications
Scalable and eco-friendly synthesis of crystalline two-dimensional (2D) polymers with
proper band gap and single-layer thickness is highly desired for the fundamental research …

Outstanding humidity chemiresistors based on imine-linked covalent organic framework films for human respiration monitoring

X Chen, L Kong, JAA Mehrez, C Fan, W Quan… - Nano-Micro Letters, 2023 - Springer
Human metabolite moisture detection is important in health monitoring and non-invasive
diagnosis. However, ultra-sensitive quantitative extraction of respiration information in real …

Manipulation of covalent organic frameworks by side-chain functionalization: toward few layer nanosheets

A De, S Haldar, S Michel, L Shupletsov… - Chemistry of …, 2023 - ACS Publications
Recent developments in the field of covalent organic frameworks (COFs) describe the issue
of processability. The precise tunability of delamination of such structures to obtain few …

Aromatic Amine-Functionalized Covalent Organic Frameworks (COFs) for CO2/N2 Separation

E Dautzenberg, G Li… - ACS Applied Materials & …, 2023 - ACS Publications
CO2 is a prominent example for an exhaust gas, and it is known for its high impact on global
warming. Therefore, carbon capture from CO2 emissions of industrial processes is …

Single Solution‐Phase Synthesis of Charged Covalent Organic Framework Nanosheets with High Volume Yield

T Huang, H Jiang, JC Douglin, Y Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Covalent organic framework nanosheets (COF‐NSs) are emerging building blocks for
functional materials, and their scalable fabrication is highly desirable. Current synthetic …