Inverse gas chromatography demonstrates the crystallinity-dependent physicochemical properties of two-dimensional covalent organic framework stationary phases

K Yusuf, A Natraj, K Li, M Ateia… - Chemistry of …, 2023 - ACS Publications
Two-dimensional polymers (2DPs), in the form of layered 2D covalent organic frameworks
(COFs), are promising candidates for adsorbent-based separations because their pore …

Beyond solvothermal: Alternative synthetic methods for covalent organic frameworks

J Hu, Z Huang, Y Liu - Angewandte Chemie International …, 2023 - Wiley Online Library
Covalent organic frameworks (COFs) are crystalline porous organic materials that hold a
wealth of potential applications across various fields. The development of COFs, however, is …

Polycrystalline covalent organic frameworks

C Qian, WL Teo, Q Gao, H Wu, Y Liao, Y Zhao - Materials Today, 2023 - Elsevier
Covalent organic frameworks (COFs) are a promising class of crystalline porous polymers
formed by reticulating organic units into two-dimensional (2D) or three-dimensional (3D) …

Single Solution‐Phase Synthesis of Charged Covalent Organic Framework Nanosheets with High Volume Yield

T Huang, H Jiang, JC Douglin, Y Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Covalent organic framework nanosheets (COF‐NSs) are emerging building blocks for
functional materials, and their scalable fabrication is highly desirable. Current synthetic …

Freestanding hydrophilic/hydrophobic Janus covalent organic framework membranes for highly efficient solar steam generation

S Jia, L Hao, Y Liu, E Lin, W Liu, Y Yang… - ACS Materials …, 2023 - ACS Publications
Solar-powered clean water production has been considered an efficient and favorable way
to address the global water shortage challenge. Herein, we design and synthesize a series …

Antiaromatic covalent organic frameworks based on dibenzopentalenes

J Sprachmann, T Wachsmuth, M Bhosale… - Journal of the …, 2023 - ACS Publications
Despite their inherent instability, 4 n π systems have recently received significant attention
due to their unique optical and electronic properties. In dibenzopentalene (DBP) …

Covalent organic frameworks: chemistry of pore interface and wall surface perturbation and impact on functions

L Deng, Z Ding, X Ye, D Jiang - Accounts of Materials Research, 2022 - ACS Publications
Conspectus Porous structures are ubiquitous, discovered in nature ranging from biological
channels in animals and plants to various pores in sediments and minerals and playing vital …

Recent advances in two-dimensional polymers: synthesis, assembly and energy-related applications

Y Ren, Y Xu - Chemical Society Reviews, 2024 - pubs.rsc.org
Two-dimensional polymers (2DPs) are a class of 2D crystalline polymer materials with
definite structures, which have outstanding physical–chemical and electronic properties …

Room temperature on-surface synthesis of a vinylene-linked single layer covalent organic framework

FG Fabozzi, N Severin, JP Rabe… - Journal of the American …, 2023 - ACS Publications
Conjugated single-layered two-dimensional covalent organic frameworks are flat and
extended polymer networks with a unique combination of material properties, giving rise to …

Controlling dynamics in extended molecular frameworks

L Feng, RD Astumian, JF Stoddart - Nature Reviews Chemistry, 2022 - nature.com
Molecular machines are essential dynamic components for fuel production, cargo delivery,
information storage and processing in living systems. Scientists have demonstrated that they …