Tailoring COFs: Transforming Nonconducting 2D Layered COF into a Conducting Quasi-3D Architecture via Interlayer Knitting with Polypyrrole

C Jain, R Kushwaha, D Rase, P Shekhar… - Journal of the …, 2023 - ACS Publications
Improving the electronic conductivity and the structural robustness of covalent organic
frameworks (COFs) is paramount. Here, we covalently cross-link a 2D COF with polypyrrole …

Two‐Dimensional Supramolecular Polymerization of a Bis‐Urea Macrocycle into a Brick‐Like Hydrogen‐Bonded Network

L Rubert, MF Islam, AB Greytak… - Angewandte Chemie …, 2023 - Wiley Online Library
We report on a dendronized bis‐urea macrocycle 1 self‐assembling via a cooperative
mechanism into two‐dimensional (2D) nanosheets formed solely by alternated urea‐urea …

Templated Synthesis of 2D Polyimide Covalent Organic Framework for Rechargeable Sodium‐Ion Batteries

MK Shehab, KS Weeraratne… - Macromolecular …, 2023 - Wiley Online Library
Covalent organic frameworks (COFs) hold great promise for electrochemical energy storage
because of their high surface area, readily accessible redox‐active sites, and environment …

Aqueous Processable Two‐Dimensional Triazine Polymers with Superior Photocatalytic Properties

T Sun, S Li, L Zhang, Y Xu - Angewandte Chemie International …, 2023 - Wiley Online Library
Efficient and scalable production of high‐quality and processable two‐dimensional (2D)
polymers are highly desired but have not yet been reported. Herein, we demonstrate a …

Water splitting catalysts using non-metal covalent organic frameworks: A review

K Dhanabalan, G Sriram, V Sannasi, KV Ajeya… - International Journal of …, 2024 - Elsevier
Hydrogen (H 2) production is essential for establishing a sustainable global ecosystem. Due
to the availability of carbon-free resources, synthesizing H 2 gas from water is currently …

Covalent Organic Frameworks: Opportunities for Rational Materials Design in Cancer Therapy

LL Zhou, Q Guan, YB Dong - … Chemie International Edition, 2024 - Wiley Online Library
Nanomedicines are extensively used in cancer therapy. Covalent organic frameworks
(COFs) are crystalline organic porous materials with several benefits for cancer therapy …

Imine-Linked 2D Conjugated Porous Organic Polymer Films for Tunable Acid Vapor Sensing

J Gayle, S Roy, S Gupta, S Hassan, A Rao… - … Applied Materials & …, 2024 - ACS Publications
Two-dimensional (2D) films of conjugated porous organic polymers (C-POPs) can translate
the rich in-plane functionalities of conjugated frameworks into diverse optical and electronic …

Expanding the horizons of covalent organic frameworks: sub-stoichiometric synthesis as an emerging toolkit for functional COFs

S Vijayakumar, A Ajayaghosh… - Journal of Materials …, 2023 - pubs.rsc.org
Covalent organic frameworks (COFs) are a class of porous materials generated from organic
molecules resulting in two-dimensional (2D) or three-dimensional (3D) networks …

Large freestanding 2D covalent organic framework nanofilms exhibiting high strength and stiffness

MF Pantano, E Missale, L Gazzato, R Pilot… - Materials Today …, 2022 - Elsevier
Two-dimensional covalent organic frameworks (2D COFs) represent an ideal platform to
develop novel technological applications. The integration of 2D COFs into thin-film device …

2D conjugated polymers: exploiting topological properties for the rational design of metal-free photocatalysts

Y Jing, X Zhu, S Maier, T Heine - Trends in Chemistry, 2022 - cell.com
Solar-to-hydrogen conversion is one of the most promising avenues to provide emission-
free fuels and long-term chemical energy storage. Wide-range application crucially requires …