The demand for practical methods for the synthesis of novel fluoroalkyl molecules is
increasing owing to their diverse applications. Our group has achieved efficient …

The electrophilic fluorination of geminal alkyl substituted vinyl‐Bmida derivatives proceeds
via bora‐Wagner–Meerwein rearrangement. According to DFT modelling studies this …

The first light-driven method for the α-trifluoromethoxylation of ketones is reported. Enol
carbonates react with N-trifluoromethoxy-4-cyano-pyridinium, using the photoredox catalyst …

Here we report a mild and general method for the trifluoromethylthiolation of aldehydes
using N-trifluoromethylthiosaccharin as the CF3S radical source and sodium decatungstate …

Reagent design is at the cornerstone of modern organofluorine chemistry. The past decades
have seen the emergence of diverse families of reagents with the aim of introducing …

The incorporation of fluorinated groups into peptides significantly affects their biophysical
properties. We report herein the synthesis of Fmoc-protected trifluoromethylthiolated tyrosine …

A catalyst‐and additive‐free decarbonylative trifluoromethylthiolation of aldehyde feedstocks
has been developed. This operationally simple, scalable, and open‐to‐air transformation is …

Comprehensive Summary A practical one‐pot preparation of carbamoyl fluorides from easily
obtained pyridine N‐oxide, commercially available secondary amines and synthetically …

We report herein a new method for the synthesis of densely functionalized chiral allyl SCF3,
SCF2R, SCN and SAr species with a separate CF3 functionality. The synthetic approach is …

Trifluoromethylselenolation of arenes with [Me4N][SeCF3] in the presence of an oxidant
through Pd-catalyzed C (sp2)–H activation under the assistance of a directing group is …