Guidelines to achieving high selectivity for the hydrogenation of α, β-unsaturated aldehydes with bimetallic and dilute alloy catalysts: a review

M Luneau, JS Lim, DA Patel, ECH Sykes… - Chemical …, 2020 - ACS Publications
Selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols is a
challenging class of reactions, yielding valuable intermediates for the production of …

Oxidation of alcohols with molecular oxygen on solid catalysts

T Mallat, A Baiker - Chemical reviews, 2004 - ACS Publications
In the past years there has been a growing demand for solid catalysts efficient in the partial
oxidation of alcohols for the production of fine and specialty chemicals. The use of …

New advances in the use of infrared absorption spectroscopy for the characterization of heterogeneous catalytic reactions

F Zaera - Chemical Society Reviews, 2014 - pubs.rsc.org
Infrared absorption spectroscopy has proven to be one of the most powerful spectroscopic
techniques available for the characterization of catalytic systems. Although the history of IR …

Chemoselective hydrogenation of carbonyl compounds over heterogeneous catalysts

P Mäki-Arvela, J Hájek, T Salmi, DY Murzin - Applied Catalysis A: General, 2005 - Elsevier
Chemoselective hydrogenation of unsaturated aldehydes and ketones over heterogeneous
catalysts is a demanding task. The achieved selectivity levels depend both on the electronic …

The surface chemistry of metal-based hydrogenation catalysis

F Zaera - ACS Catalysis, 2017 - ACS Publications
The promotion of hydrogenation reactions by transition-metal-based heterogeneous
catalysts was established many decades ago but is still quite common in the chemical …

Control of metal catalyst selectivity through specific noncovalent molecular interactions

KR Kahsar, DK Schwartz… - Journal of the American …, 2014 - ACS Publications
The specificity of chemical reactions conducted over solid catalysts can potentially be
improved by utilizing noncovalent interactions to direct reactant binding geometry. Here we …

Kinetics of liquid-phase hydrogenation reactions over supported metal catalysts—a review

UK Singh, MA Vannice - Applied Catalysis A: General, 2001 - Elsevier
The kinetics of liquid-phase hydrogenation reactions have been reviewed with a special
emphasis on α, β-unsaturated aldehydes as reactants. These reactions can be complex and …

Role of Lewis and Brønsted acid sites in the dehydration of glycerol over niobia

GS Foo, D Wei, DS Sholl, C Sievers - Acs Catalysis, 2014 - ACS Publications
The role of Lewis and Brønsted sites in the dehydration of glycerol on niobium oxide and
Na+-exchanged niobium oxide is investigated using FTIR spectroscopy supported by DFT …

Kinetic and mechanistic study of bimetallic Pt-Pd/Al2O3 catalysts for CO and C3H6 oxidation

MJ Hazlett, M Moses-Debusk, JE Parks II… - Applied Catalysis B …, 2017 - Elsevier
Low temperature combustion (LTC) diesel engines are being developed to meet increased
fuel economy demands. However, some LTC engines emit higher levels of CO and …

Organic chemistry on solid surfaces

Z Ma, F Zaera - Surface science reports, 2006 - Elsevier
Chemistry on solid surfaces is central to many areas of practical interest such as
heterogeneous catalysis, tribology, electrochemistry, and materials processing. With the …