Surface Chemistry of Perovskite-Type Electrodes During High Temperature CO2 Electrolysis Investigated by Operando Photoelectron Spectroscopy

AK Opitz, A Nenning, C Rameshan… - … applied materials & …, 2017 - ACS Publications
Any substantial move of energy sources from fossil fuels to renewable resources requires
large scale storage of excess energy, for example, via power to fuel processes. In this …

Nickel enriched Ruddlesden-Popper type lanthanum strontium manganite as electrode for symmetrical solid oxide fuel cell

Z Xu, Y Li, Y Wan, S Zhang, C Xia - Journal of Power Sources, 2019 - Elsevier
Abstract Ruddlesden− Popper type oxide, La 0.5 Sr 1.5 MnO 4+ δ, is investigated as a
potential electrode material for symmetrical solid oxide fuel cells. This work improves its …

Diving deep into solid oxide-based CO2 electrolysis: Operando insights

V Kamboj, S Raychowdhury, C Ranjan - Current Opinion in …, 2024 - Elsevier
CO 2 reduction to fuels using solid oxide electrodes is a promising approach due to high
faradaic and energy efficiencies. CO 2 reducing electrodes (cathodes) form the central …

[HTML][HTML] Oxygen exchange kinetics and nonstoichiometry of pristine La 0.6 Sr 0.4 CoO 3− δ thin films unaltered by degradation

M Siebenhofer, TM Huber, G Friedbacher… - Journal of Materials …, 2020 - pubs.rsc.org
La0. 6Sr0. 4CoO3− δ thin films grown on YSZ single crystals were investigated directly in the
stage of deposition by means of in situ impedance spectroscopy during pulsed laser …

How to get mechanistic information from partial pressure-dependent current–voltage measurements of oxygen exchange on mixed conducting electrodes

A Schmid, GM Rupp, J Fleig - Chemistry of Materials, 2018 - ACS Publications
The oxygen incorporation and evolution reaction on mixed conducting electrodes of solid
oxide fuel or electrolysis cells involves gas molecules as well as ionic and electronic point …

[HTML][HTML] Exsolved catalyst particles as a plaything of atmosphere and electrochemistry

H Summerer, A Nenning, C Rameshan, AK Opitz - Ees Catalysis, 2023 - pubs.rsc.org
A new type of catalyst preparation yields its active sites not by infiltration but exsolution of
reducible transition metals of its own host lattice. These exsolution catalysts offer a high …

Differentiating Oxygen Exchange Reaction Mechanisms across Phase Boundaries

K Yang, Y Lu, Y Hu, Z Xu, J Zheng… - Journal of the …, 2023 - ACS Publications
Triggering phase transitions by controlling the anion stoichiometry is an effective method of
tuning the electrocatalytic activity of the functional oxides. However, understanding the …

The current-voltage characteristics and partial pressure dependence of defect controlled electrochemical reactions on mixed conducting oxides

A Schmid, J Fleig - Journal of The Electrochemical Society, 2019 - iopscience.iop.org
Electrochemical reactions at solid| gas interfaces of mixed ionic electronic conductors
(MIEC), such as oxygen reduction or evolution, differ substantially from usual …

In Situ Impedance Analysis of Oxygen Exchange on Growing La0.6Sr0.4CoO3−δ Thin Films

GM Rupp, M Kubicek, AK Opitz… - ACS applied energy …, 2018 - ACS Publications
The further development of solid oxide fuel and electrolysis cells (SOFC/SOEC) strongly
relies on research activities dealing with electrode materials. Recent studies showed that …

Analyzing the dependence of oxygen incorporation current density on overpotential and oxygen partial pressure in mixed conducting oxide electrodes

Z Guan, D Chen, WC Chueh - Physical Chemistry Chemical Physics, 2017 - pubs.rsc.org
The oxygen incorporation reaction, which involves the transformation of an oxygen gas
molecule to two lattice oxygen ions in a mixed ionic and electronic conducting solid, is a …