Molecular catalysts with diphosphine ligands containing pendant amines
Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …
Hydrogenases
The reaction takes place at a specialized metal center that dramatically increases the acidity
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …
Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2 nd sphere interactions in catalysis
Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …
importance as they are crucial for a sustainable environment. Substantial research has been …
Development of molecular electrocatalysts for energy storage
DL DuBois - Inorganic chemistry, 2014 - ACS Publications
Molecular electrocatalysts can play an important role in energy storage and utilization
reactions needed for intermittent renewable energy sources. This manuscript describes …
reactions needed for intermittent renewable energy sources. This manuscript describes …
Brønsted–Lowry acid strength of metal hydride and dihydrogen complexes
RH Morris - Chemical Reviews, 2016 - ACS Publications
Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …
Iron (II) complexes containing unsymmetrical P–N–P′ pincer ligands for the catalytic asymmetric hydrogenation of ketones and imines
PO Lagaditis, PE Sues, JF Sonnenberg… - Journal of the …, 2014 - ACS Publications
After their treatment with LiAlH4 and then alcohol, new iron dicarbonyl complexes mer-trans-
[Fe (Br)(CO) 2 (P–CH N–P′)][BF4](where P–CH N–P′= R2PCH2CH NCH2CH2PPh2 …
[Fe (Br)(CO) 2 (P–CH N–P′)][BF4](where P–CH N–P′= R2PCH2CH NCH2CH2PPh2 …
Dihydrogen complexation
RH Crabtree - Chemical Reviews, 2016 - ACS Publications
Dihydrogen complexation with retention of the H–H bond, once an exotic concept, has by
now appeared in a very wide range of contexts. Three structural types are currently …
now appeared in a very wide range of contexts. Three structural types are currently …
Hydrogen and dihydrogen bonds in the reactions of metal hydrides
NV Belkova, LM Epstein, OA Filippov… - Chemical …, 2016 - ACS Publications
The dihydrogen bond an interaction between a transition-metal or main-group hydride (M
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …
Production of hydrogen by electrocatalysis: making the H–H bond by combining protons and hydrides
RM Bullock, AM Appel, ML Helm - Chemical Communications, 2014 - pubs.rsc.org
Generation of hydrogen by reduction of two protons by two electrons can be catalysed by
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …
Coordination-driven electrocatalysts as an evolving wave of enthusiasm for sustainable hydrogen production
Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …
fuel alternatives. Commercial-scale hydrogen production through water-splitting …