[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Recent advances in crystalline hybrid photochromic materials driven by electron transfer

SD Han, JX Hu, GM Wang - Coordination Chemistry Reviews, 2022 - Elsevier
Photochromic materials have broad application prospects in the fields of molecular
switching, detection, biological, and molecular machines. Crystalline hybrid photochromic …

Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

FS Guo, BM Day, YC Chen, ML Tong, A Mansikkamäki… - Science, 2018 - science.org
Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …

Manipulating on/off single-molecule magnet behavior in a Dy (III)-based photochromic complex

YJ Ma, JX Hu, SD Han, J Pan, JH Li… - Journal of the American …, 2020 - ACS Publications
Exploitation of room temperature (RT) photochromism and photomagnetism to induce single-
molecule magnet (SMM) behavior has potential applications toward optical switches and …

A Complete Ab Initio View of Orbach and Raman Spin–Lattice Relaxation in a Dysprosium Coordination Compound

M Briganti, F Santanni, L Tesi, F Totti… - Journal of the …, 2021 - ACS Publications
The unique electronic and magnetic properties of lanthanide molecular complexes place
them at the forefront of the race toward high-temperature single-molecule magnets and …

A High-Performance Single-Molecule Magnet Utilizing Dianionic Aminoborolide Ligands

JC Vanjak, BO Wilkins, V Vieru… - Journal of the …, 2022 - ACS Publications
The first example of a homoleptic f-block borolide sandwich complex is presented and
shown to be a high-performance single-molecule magnet (SMM). The bis (borolide) complex …

High-temperature magnetic blocking and magneto-structural correlations in a series of dysprosium (III) metallocenium single-molecule magnets

KR McClain, CA Gould, K Chakarawet, SJ Teat… - Chemical …, 2018 - pubs.rsc.org
A series of dysprosium (III) metallocenium salts,[Dy (CpiPr4R) 2][B (C6F5) 4](R= H (1), Me
(2), Et (3), iPr (4)), was synthesized by reaction of DyI3 with the corresponding known …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Rare-earth based tetrapyrrolic sandwiches: chemistry, materials and applications

AG Martynov, Y Horii, K Katoh, Y Bian, J Jiang… - Chemical Society …, 2022 - pubs.rsc.org
The unique properties of natural tetrapyrrolic compounds have inspired the rapid growth of
research interest in the design and synthesis of artificial porphyrinoids and their metal …

Spin–phonon coupling and magnetic relaxation in single-molecule magnets

JGC Kragskow, A Mattioni, JK Staab, D Reta… - Chemical Society …, 2023 - pubs.rsc.org
Electron–phonon coupling is important in many physical phenomena, eg photosynthesis,
catalysis and quantum information processing, but its impacts are difficult to grasp on the …