Atomically precise imprinting π-magnetism in nanographenes via probe chemistry

J Su, P Lyu, J Lu - Precision Chemistry, 2023 - ACS Publications
The precise generation and harnessing of carbon magnetism at the single-molecule level
have been captivating areas of research in chemistry and nanotechnology. However, the …

Atomic-Limit Mott Insulator in [4] Triangulene Frameworks

T Fang, T Zhang, T Hu, Z Wang - Nano Letters, 2024 - ACS Publications
Triangulene, one unique class of zigzag-edged triangular graphene molecules, has
attracted tremendous research interest. In this work, as an ultimate phase of the Mott …

Topological Structure Realized in Cove-Edged Graphene Nanoribbons via Incorporation of Periodic Pentagon Rings

X Zhu, K Li, J Liu, Z Wang, Z Ding, Y Su… - Journal of the …, 2024 - ACS Publications
Cove-edged zigzag graphene nanoribbons are predicted to show metallic, topological, or
trivial semiconducting band structures, which are precisely determined by their cove offset …

Steering Electron-Induced Surface Reaction via a Molecular Assembly Approach

Y Lin, J Li, X Liang, T Hu, Z Huang, Z Zhu… - Journal of the …, 2024 - ACS Publications
Electrons not only serve as a “reactant” in redox reactions but also play a role in “catalyzing”
some chemical processes. Despite the significance and ubiquitousness of electron-induced …

Regioselective 2, 3-disubstituted porphyrins: synthesis, spectral, structural and electrochemical properties

W Arif, R Kumar - New Journal of Chemistry, 2023 - pubs.rsc.org
A series of regioselective β-disubstituted meso-tetraphenylporphyrins, H2TPP (X) 2 (where
X= methyl (CH3), phenyl (Ph), bromo (Br) and phenylethynyl (PE)), as well their metal …

Quantum spin helices more stable than the ground state: Onset of helical protection

S Kühn, F Gerken, L Funcke, T Hartung, P Stornati… - Physical Review B, 2023 - APS
Topological magnetic structures are promising candidates for resilient information storage.
An elementary example is spin helices in one-dimensional easy-plane quantum magnets …

Intelligent synthesis of magnetic nanographenes via chemist-intuited atomic robotic probe

J Su, J Li, N Guo, X Peng, J Yin, J Wang, P Lyu… - Nature …, 2024 - nature.com
Atomic-scale manufacturing of carbon-based quantum materials with single-bond precision
holds immense potential in advancing tailor-made quantum materials with unconventional …

Unraveling the Nature of Spin Coupling in a Metal-Free Diradical: Theoretical Distinction of Ferromagnetic and Antiferromagnetic Interactions

L Zuo, L Ye, X Li, RX Xu, YJ Yan… - The Journal of Physical …, 2024 - ACS Publications
Metal-free diradicals based on polycyclic aromatic hydrocarbons are promising candidates
for organic spintronics due to their stable magnetism and tunable spin coupling. However …

Length‐Dependent Magnetic Evolution of Anthenes on Au (111)

H Zhang, J Lu, XJ Zhao, B Li, H Zhou… - Angewandte …, 2023 - Wiley Online Library
Nanographenes with zigzag edges, for example, anthenes, exhibit a unique nonbonding π‐
electron state, which can be described as a spin‐polarized edge state that yields specific …

Antiferromagnetic spin-1 large-D phase in organic spin-chain crystals

Z Li, Y Wang, Y Han, M Song, J Song, J Li… - Journal of Materials …, 2023 - pubs.rsc.org
Low-dimensional magnetism, including the Haldane phase and large single ion anisotropy
(large-D) phase, has received ongoing attention due to their potential applications in …