Vanadium is a trace element, which may be beneficial and possibly essential in humans1
but certainly essential for some living organisms. 2r11 Metal ions and thus vanadium ions …

In the field of asymmetric synthesis, nonracemic sulfoxides are recognized as valuable and
efficient reagents. Their extensive use as chiral auxiliaries and intermediates is …

V2O5 nanowires exhibit an intrinsic catalytic activity towards classical peroxidase substrates
such as 2, 2‐azino‐bis (3‐ethylbenzothiazoline‐6‐sulfonic acid)(ABTS) and 3, 3, 5, 5 …

A longstanding goal of biomimetic chemistry is the design and synthesis of functional
enzyme mimics. The past three decades have seen a wide variety of materials, including …

Covering: 1998–2003 Halogenated natural products are frequently reported metabolites in
marine seaweeds. These compounds span a range from halogenated indoles, terpenes …

The importance of vanadium in life processes is addressed, emphasising the vanadium
cofactors in vanadate-dependent haloperoxidases and vanadium-nitrogenases. Structural …

Vanadium haloperoxidases catalyse the oxidation of halides leading to halogenation of
substrates or, in the absence of suitable substrates, to oxidation of hydrogen peroxide into …

This Handbook on Metalloproteins focuses on the available structural information of proteins
and their metal ion coordination spheres. It centers on the metal ions indispensable for life …

The homo-dimeric structure of a vanadium-dependent haloperoxidase (V-BPO) from the
brown alga Ascophyllum nodosum (EC 1.1. 11. X) has been solved by single isomorphous …

Peroxygenases enable H2O2-driven oxyfunctionalisation of organic compounds such as
selective epoxidation, hydroxylation and heteroatom oxygenation. Therefore …