Understanding the interplay of multiple components (steric, electrostatic, stereoelectronic,
dispersive, etc.) that define the overall energy, structure, and reactivity of organic molecules …

Photoredox catalysis has recently emerged as a powerful synthetic platform for accessing
complex chemical structures through non-traditional bond disconnection strategies that …

Reactions that enable selective functionalization of strong aliphatic C–H bonds open new
synthetic paths to rapidly increase molecular complexity and expand chemical space …

We report herein a protocol for the selective activation of C (sp 3)–H bonds based on the
interplay of two readily available organic catalysts and their successful implementation in …

In this study, a novel nano-magnetic metal–organic frameworks based on Fe3O4 namely
Fe3O4@ MIL-101 (Cr)-N (CH2PO3) 2 was synthesized and fully characterized. The …

In this paper, the MIL-53 (Al)-NH2 metal–organic frameworks (MOFs) was prepared based
on the anodic electrosynthesis under green conditions. The anodic electrosynthesis as an …

As the simplest alkyne and an abundant chemical feedstock, acetylene is an ideal two-
carbon building block. However, in contrast to substituted alkynes, catalytic methods to …

In order to use holes as catalysts, the oxidized product should be able to transfer the hole to
a fresh reactant. For that, the hole-catalyzed reaction must increase the oxidation potential …

Herein, we report the design and synthesis of Co-MOF-71/imidazole/SO3H as a novel
porous catalyst with sulfonic acid tags. The structure and morphology of the catalyst were …

We show that the carboxylate radical acts as an L-ligand with certain high-spin transition
metal centers. Such coordination preserves the O-radical character needed for C–H …