Artificial biocatalytic linear cascades for preparation of organic molecules

JH Schrittwieser, S Velikogne, M Hall… - Chemical …, 2018 - ACS Publications
The review compiles artificial cascades involving enzymes with a focus on the last 10 years.
A cascade is defined as the combination of at least two reaction steps in a single reaction …

Combinations of aminocatalysts and metal catalysts: a powerful cooperative approach in selective organic synthesis

S Afewerki, A Cordova - Chemical reviews, 2016 - ACS Publications
The cooperation and interplay between organic and metal catalyst systems is of utmost
importance in nature and chemical synthesis. Here innovative and selective cooperative …

Facile synthesis of multiple enzyme-containing metal–organic frameworks in a biomolecule-friendly environment

X Wu, J Ge, C Yang, M Hou, Z Liu - Chemical Communications, 2015 - pubs.rsc.org
The one-step and facile synthesis of multi-enzyme-containing metal–organic framework
(MOF) nanocrystals in aqueous solution at 25° C was reported in this study. The …

Amorphous Fe-containing phosphotungstates featuring efficient peroxidase-like activity at neutral pH: toward portable swabs for pesticide detection with tandem …

H Zhu, B Liu, M Wang, J Pan, L Xu, P Hu… - Analytical …, 2023 - ACS Publications
Peroxidase-mimetic materials are intensively applied to establish multienzyme systems
because of their attractive merits. However, almost all of the nanozymes explored exhibit …

Enzymatic cascade reactions in biosynthesis

CT Walsh, BS Moore - Angewandte Chemie International …, 2019 - Wiley Online Library
Enzyme‐mediated cascade reactions are widespread in biosynthesis. To facilitate
comparison with the mechanistic categorizations of cascade reactions by synthetic chemists …

Tandem construction of biological relevant aliphatic 5-membered N-heterocycles

D Łowicki, P Przybylski - European Journal of Medicinal Chemistry, 2022 - Elsevier
Nature often uses cascade reactions in a highly stereocontrolled manner for assembly
structurally diverse nitrogen-containing heterocyclic scaffolds, ie secondary metabolites …

Recent developments in enantioselective multicatalysed tandem reactions

H Pellissier - Tetrahedron, 2013 - Elsevier
This review updates enantioselective multicatalysed tandem reactions covering the literature
since the beginning of 2010. This compilation clearly demonstrates that the concept of …

Epoxidation catalyzed by the nonheme iron (II)-and 2-oxoglutarate-dependent oxygenase, AsqJ: Mechanistic elucidation of oxygen atom transfer by a ferryl …

J Li, HJ Liao, Y Tang, JL Huang, L Cha… - Journal of the …, 2020 - ACS Publications
Mechanisms of enzymatic epoxidation via oxygen atom transfer (OAT) to an olefin moiety is
mainly derived from the studies on thiolate-heme containing epoxidases, such as …

Cascade reactions catalyzed by bionanostructures

M Filice, JM Palomo - ACS Catalysis, 2014 - ACS Publications
Cascade reactions are an emerging technology in organic chemistry, introducing elegance
and efficiency to synthetic strategies. This Review provides an overview of the novel and …

Biogenetic and biomimetic synthesis of natural bisditerpenoids: hypothesis and practices

Y Chang, C Sun, C Wang, X Huo, W Zhao… - Natural Product …, 2022 - pubs.rsc.org
Covering: up to March 2022 Bisditerpenoids, or diterpenoid dimers, are a group of natural
products with high structural variance, deriving from homo-or hetero-dimeric coupling of two …