The many flavours of mechanochemistry and its plausible conceptual underpinnings
RT O'Neill, R Boulatov - Nature Reviews Chemistry, 2021 - nature.com
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …
chemical reactivity. The fuzziness of this definition means that it includes processes as …
[HTML][HTML] Stimuli-responsive structure–property switchable polymer materials
The development of polymeric materials with switchable properties upon exposure to
external stimuli such as light, heat, force, acids/bases, and chemicals has attracted much …
external stimuli such as light, heat, force, acids/bases, and chemicals has attracted much …
Polymer mechanochemistry in microbubbles
M Xuan, J Fan, VN Khiêm, M Zou… - Advanced …, 2023 - Wiley Online Library
Polymer mechanochemistry is a promising technology to convert mechanical energy into
chemical functionality by breaking covalent and supramolecular bonds site‐selectively. Yet …
chemical functionality by breaking covalent and supramolecular bonds site‐selectively. Yet …
Mechanically responsive luminescent polymers based on supramolecular cyclophane mechanophores
A new approach to cyclophane-based supramolecular mechanophores is presented. We
report a mechanically responsive cyclic motif that contains two fluorescent 1, 6-bis …
report a mechanically responsive cyclic motif that contains two fluorescent 1, 6-bis …
Rotaxane-based dual function mechanophores exhibiting reversible and irreversible responses
T Muramatsu, Y Okado, H Traeger… - Journal of the …, 2021 - ACS Publications
Mechanochromic mechanophores permit the design of polymers that indicate mechanical
events through optical signals. Here we report rotaxane-based supramolecular …
events through optical signals. Here we report rotaxane-based supramolecular …
Folded perylene diimide loops as mechanoresponsive motifs
A supramolecular mechanophore that can be integrated into polymers and indicates
deformation by a fluorescence color change is reported. Two perylene diimides (PDIs) were …
deformation by a fluorescence color change is reported. Two perylene diimides (PDIs) were …
Conformer Ring Flip Enhances Mechanochromic Performance of ansa-Donor–Acceptor–Donor Mechanochromic Torsional Springs
R Hertel, W Maftuhin, M Walter… - Journal of the American …, 2022 - ACS Publications
Mechanochromophores based on conformational changes of donor–acceptor–donor (DAD)
springs allow sensing of forces acting on polymer chains by monotonic changes of …
springs allow sensing of forces acting on polymer chains by monotonic changes of …
Excited State Charge‐Transfer Complexes Enable Fluorescence Color Changes in a Supramolecular Cyclophane Mechanophore
S Thazhathethil, T Muramatsu, N Tamaoki… - Angewandte …, 2022 - Wiley Online Library
Mechanochromic mechanophores are reporter molecules that indicate mechanical events
through changes of their photophysical properties. Supramolecular mechanophores in …
through changes of their photophysical properties. Supramolecular mechanophores in …
[HTML][HTML] A review of mechanochromic polymers and composites: From material design strategy to advanced electronics application
Q Guo, X Zhang - Composites Part B: Engineering, 2021 - Elsevier
The design and fabrication of functional polymers with fascinating mechanochromic
properties are of profound significance to their prospective applications, such as wearable …
properties are of profound significance to their prospective applications, such as wearable …
[HTML][HTML] Halogen bonding in polymer science: towards new smart materials
The halogen bond is a special non-covalent interaction, which can represent a powerful tool
in supramolecular chemistry. Although the halogen bond offers several advantages …
in supramolecular chemistry. Although the halogen bond offers several advantages …