Molecular characterization of polymer networks

SPO Danielsen, HK Beech, S Wang… - Chemical …, 2021 - ACS Publications
Polymer networks are complex systems consisting of molecular components. Whereas the
properties of the individual components are typically well understood by most chemists …

Kinetics and mechanisms of thiol–disulfide exchange covering direct substitution and thiol oxidation-mediated pathways

P Nagy - Antioxidants & redox signaling, 2013 - liebertpub.com
Significance: Disulfides are important building blocks in the secondary and tertiary structures
of proteins, serving as inter-and intra-subunit cross links. Disulfides are also the major …

Covalent mechanochemistry: theoretical concepts and computational tools with applications to molecular nanomechanics

J Ribas-Arino, D Marx - Chemical reviews, 2012 - ACS Publications
In the following section, we will recapitulate selected experimental milestones through the
eyes of the theoretician, which, in our opinion, significantly advanced the field of covalent …

Mechanical control of nanomaterials and nanosystems

K Ariga, T Mori, JP Hill - Advanced materials, 2012 - Wiley Online Library
In situations of power outage or shortage, such as periods just following a seismic disaster,
the only reliable power source available is the most fundamental of forces ie, manual …

Mechanochemistry: the varied applications of mechanical bond-breaking

G Kaupp - CrystEngComm, 2009 - pubs.rsc.org
Mechanochemistry means mechanical breakage of intramolecular bonds by external force
and must be differentiated from molecular solid-state chemistry, where contacts between …

Outstanding advantages, current drawbacks, and significant recent developments in mechanochemistry: a perspective view

S Pagola - Crystals, 2023 - mdpi.com
Although known since antiquity, mechanochemistry has remained dormant for centuries.
Nowadays, mechanochemistry is a flourishing research field at the simultaneous stages of …

From molecular mechanochemistry to stress-responsive materials

AL Black, JM Lenhardt, SL Craig - Journal of Materials Chemistry, 2011 - pubs.rsc.org
Current activity in, and future prospects for, the incorporation of mechanochemically active
functional groups (“mechanophores”) into polymers is reviewed. This area of research is …

Influence of cross-linkers on the cohesive and adhesive self-healing ability of polysulfide-based thermosets

U Lafont, H Van Zeijl… - ACS applied materials & …, 2012 - ACS Publications
Synthetic systems with intrinsic self-repairing or self-healing abilities have emerged during
the past decade. In this work, the influence of the cross-linker and chain rigidity on the …

Trapping a diradical transition state by mechanochemical polymer extension

JM Lenhardt, MT Ong, R Choe, CR Evenhuis… - Science, 2010 - science.org
Transition state structures are central to the rates and outcomes of chemical reactions, but
their fleeting existence often leaves their properties to be inferred rather than observed. By …

Understanding covalent mechanochemistry

J Ribas‐Arino, M Shiga, D Marx - … Chemie International Edition, 2009 - Wiley Online Library
Understanding Covalent Mechanochemistry - Ribas‐Arino - 2009 - Angewandte Chemie
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