Abstract The Friedel‐Crafts reaction stands as a powerful synthetic tool for C− H
functionalization of aromatic feedstocks, which is conventionally realized through …

Axially chiral architectures exist widely in natural products, biologically relevant molecules,
chiral ligands and catalysts as well as functional materials. Therefore, catalytic asymmetric …

An efficient catalytic asymmetric electrophilic sulfenylation reaction for the synthesis of
planar‐chiral sulfur‐containing cyclophanes has been developed for the first time. This was …

We herein introduce biarylhemiboronic esters as a new type of bridged biaryl reagent for
asymmetric synthesis of axially chiral biaryl structures, and the palladium-catalyzed …

Upgrading CO2 to value‐added chiral molecules via catalytic asymmetric C− C bond
formation is a highly important yet challenging task. Although great progress on the …

A dynamic thermodynamic resolution method for converting (R/S)-BINOL (1, 1′-binaphthyl-
2, 2′-diol) into (R)-BINOL in 100% theoretical yield is reported. This technique involves …

This work sheds new light on the stereoselective synthesis of chiral macrocycles containing
twisted aromatic units, valuable π-conjugated materials for recognition, sensing, and …

Herein, multiple types of chiral Os (II) complexes have been designed to address the
appealing yet challenging asymmetric C (sp3)− H functionalization, among which the Os …

Axially chiral carboxylic acids are important motifs in chiral catalysts and ligands. We herein
reported the synthesis of axially chiral carboxylic acids via Pd (II)-catalyzed atroposelective …

Axially chiral biaryls featuring a C–N axis are important functional molecules in diverse
fields. The asymmetric Buchwald–Hartwig reaction represents a powerful strategy for these …