The E factor at 30: a passion for pollution prevention

RA Sheldon - Green Chemistry, 2023 - pubs.rsc.org
The introduction of the E Factor in 1992 focussed attention on the problem of waste
generation, defined as everything but the desired product, in chemicals manufacture and …

Green chemistry, biocatalysis, and the chemical industry of the future

RA Sheldon, D Brady - ChemSusChem, 2022 - Wiley Online Library
In the movement to decarbonize our economy and move away from fossil fuels we will need
to harness the waste products of our activities, such as waste lignocellulose, methane, and …

Bacteria–photocatalyst sheet for sustainable carbon dioxide utilization

Q Wang, S Kalathil, C Pornrungroj, CD Sahm… - Nature Catalysis, 2022 - nature.com
The clean conversion of carbon dioxide and water to a single multicarbon product and O2
using sunlight via photocatalysis without the assistance of organic additives or electricity …

Fast CO2 hydration kinetics impair heterogeneous but improve enzymatic CO2 reduction catalysis

SJ Cobb, VM Badiani, AM Dharani, A Wagner… - Nature …, 2022 - nature.com
The performance of heterogeneous catalysts for electrocatalytic CO2 reduction suffers from
unwanted side reactions and kinetic inefficiencies at the required large overpotential …

From protein film electrochemistry to nanoconfined enzyme cascades and the electrochemical leaf

FA Armstrong, B Cheng, RA Herold… - Chemical …, 2022 - ACS Publications
Protein film electrochemistry (PFE) has given unrivalled insight into the properties of redox
proteins and many electron-transferring enzymes, allowing investigations of otherwise ill …

Bioelectrocatalytic Synthesis: Concepts and Applications

DG Boucher, E Carroll, ZA Nguyen… - Angewandte …, 2023 - Wiley Online Library
Bioelectrocatalytic synthesis is the conversion of electrical energy into value‐added
products using biocatalysts. These methods merge the specificity and selectivity of …

Exploring Emergent Properties in Enzymatic Reaction Networks: Design and Control of Dynamic Functional Systems

S Ghosh, MG Baltussen, NM Ivanov, R Haije… - Chemical …, 2024 - ACS Publications
The intricate and complex features of enzymatic reaction networks (ERNs) play a key role in
the emergence and sustenance of life. Constructing such networks in vitro enables stepwise …

Construction of macroporous β-glucosidase@ mofs by a metal competitive coordination and oxidation strategy for efficient cellulose conversion at 120 C

R Jiao, Y Wang, Y Pang, D Yang, Z Li… - ACS Applied Materials …, 2023 - ACS Publications
Metal–organic frameworks (MOFs) have become promising accommodation for enzyme
immobilization in recent years. However, the microporous nature of MOFs affects the …

NADP (H)-dependent biocatalysis without adding NADP (H)

RA Herold, R Reinbold, CJ Schofield… - Proceedings of the …, 2023 - National Acad Sciences
Isocitrate dehydrogenase 1 (IDH1) naturally copurifies and crystallizes in a resting state with
a molecule of its exchangeable cofactor, NADP+/NADPH, bound in each monomer of the …

Bioelectrocatalytic Cofactor Regeneration Coupled to CO2 Fixation in a Redox‐Active Hydrogel for Stereoselective C−C Bond Formation

L Castañeda‐Losada, D Adam… - Angewandte Chemie …, 2021 - Wiley Online Library
The sustainable capture and conversion of carbon dioxide (CO2) is key to achieving a
circular carbon economy. Bioelectrocatalysis, which aims at using renewable energies to …