Directing coupled motion with light: a key step toward machine-like function
Molecular photoactuators can control shape and chemical or physical properties of the
responsive system they are embedded in. These effects are usually mediated by …
responsive system they are embedded in. These effects are usually mediated by …
Functional dynamics in framework materials
Dynamic crystalline materials have emerged as a unique category of condensed phase
matter that combines crystalline lattice with components that display dynamic behavior in the …
matter that combines crystalline lattice with components that display dynamic behavior in the …
Modulation of Rotational Dynamics in Halogen-Bonded Cocrystalline Solids
SS Gunaga, DL Bryce - Journal of the American Chemical Society, 2023 - ACS Publications
Dynamic processes are responsible for the functionality of a range of materials,
biomolecules, and catalysts. We report a detailed systematic study of the modulation of …
biomolecules, and catalysts. We report a detailed systematic study of the modulation of …
Recent advances on triptycene derivatives in supramolecular and materials chemistry
MJ Gu, YF Wang, Y Han, CF Chen - Organic & Biomolecular Chemistry, 2021 - pubs.rsc.org
Triptycene derivatives, a type of specific aromatic compound, have been attracting much
attention in many research areas. Over the past several years, triptycene and its derivatives …
attention in many research areas. Over the past several years, triptycene and its derivatives …
Benchmark Dynamics of Dipolar Molecular Rotors in Fluorinated Metal‐Organic Frameworks
Abstract Fluorinated Metal‐Organic Frameworks (MOFs), comprising a wheel‐shaped ligand
with geminal rotating fluorine atoms, produced benchmark mobility of correlated dipolar …
with geminal rotating fluorine atoms, produced benchmark mobility of correlated dipolar …
Molecular gears: from solution to surfaces
Y Gisbert, S Abid, C Kammerer… - Chemistry–A European …, 2021 - Wiley Online Library
This review highlights the major efforts devoted to the development of molecular gears over
the past 40 years, from pioneering covalent bis‐triptycyl systems undergoing intramolecular …
the past 40 years, from pioneering covalent bis‐triptycyl systems undergoing intramolecular …
Bifurcated Polymorphic Transition and Thermochromic Fluorescence of a Molecular Crystal Involving Three-Dimensional Supramolecular Gear Rotation
YH Yang, YS Chen, WT Chuang… - Journal of the American …, 2024 - ACS Publications
The ability of molecules to move and rearrange in the solid state accounts for the
polymorphic transition and stimuli-responsive properties of molecular crystals. However …
polymorphic transition and stimuli-responsive properties of molecular crystals. However …
Photogearing as a concept for translation of precise motions at the nanoscale
A Gerwien, F Gnannt, P Mayer, H Dube - Nature Chemistry, 2022 - nature.com
One of the major challenges for harnessing the true potential of functional nano-machinery
is integrating and transmitting motion with great precision. Molecular gearing systems …
is integrating and transmitting motion with great precision. Molecular gearing systems …
Giant crystalline molecular rotors that operate in the solid state
R Ando, A Sato‐Tomita, H Ito, M Jin - Angewandte Chemie, 2023 - Wiley Online Library
Molecular motion in the solid state is typically precluded by the highly dense environment,
and only molecules with a limited range of sizes show such dynamics. Here, we …
and only molecules with a limited range of sizes show such dynamics. Here, we …
A ferroelastic molecular rotor crystal showing inverse temperature symmetry breaking
LP Miao, LL Chu, XB Han, BD Liang, CY Chai… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Functional dynamic molecular crystals have drawn increasing interest in exploring next-
generation flexible and smart materials. Molecular rotors, as a typical type of dynamic …
generation flexible and smart materials. Molecular rotors, as a typical type of dynamic …