Aromatic hydrocarbon belts

QH Guo, Y Qiu, MX Wang, J Fraser Stoddart - Nature chemistry, 2021 - nature.com
Aromatic hydrocarbon belts (AHCBs) have fascinated scientists for over half a century
because of their aesthetically appealing structures and potential applications in the field of …

Synthesis and Properties of 2D Carbon Graphdiyne

Z Jia, Y Li, Z Zuo, H Liu, C Huang… - Accounts of chemical …, 2017 - ACS Publications
Conspectus Graphdiyne (GDY) is a flat material comprising sp2-and sp-hybridized carbon
atoms with high degrees of π conjugation that features uniformly distributed pores. It is …

An sp-hybridized all-carboatomic ring, cyclo [18] carbon: Electronic structure, electronic spectrum, and optical nonlinearity

Z Liu, T Lu, Q Chen - Carbon, 2020 - Elsevier
The electronic spectrum and optical nonlinearity of the sp-hybridized cyclo [18] carbon with
novel topology are studied by means of (time-dependent) density functional theory …

An sp-hybridized molecular carbon allotrope, cyclo [18] carbon

K Kaiser, LM Scriven, F Schulz, P Gawel, L Gross… - Science, 2019 - science.org
Carbon allotropes built from rings of two-coordinate atoms, known as cyclo [n] carbons, have
fascinated chemists for many years, but until now they could not be isolated or structurally …

An sp-hybridized all-carboatomic ring, cyclo [18] carbon: Bonding character, electron delocalization, and aromaticity

Z Liu, T Lu, Q Chen - Carbon, 2020 - Elsevier
Abstract cyclo [18] carbon is an all-carboatomic ring observed recently in experiment.
Inspired by the distinctive feature in structure and bonding nature, we explored …

Clip chemistry: diverse (bio)(macro) molecular and material function through breaking covalent bonds

P Shieh, MR Hill, W Zhang, SL Kristufek… - Chemical …, 2021 - ACS Publications
In the two decades since the introduction of the “click chemistry” concept, the toolbox of “click
reactions” has continually expanded, enabling chemists, materials scientists, and biologists …

[HTML][HTML] Artificial intelligence-enhanced quantum chemical method with broad applicability

P Zheng, R Zubatyuk, W Wu, O Isayev… - Nature communications, 2021 - nature.com
High-level quantum mechanical (QM) calculations are indispensable for accurate
explanation of natural phenomena on the atomistic level. Their staggering computational …

Synthesis of π-conjugated chiral organoborane macrocycles with blue to near-infrared emissions and the diradical character of cations

F Zhao, J Zhao, H Liu, Y Wang, J Duan… - Journal of the …, 2023 - ACS Publications
Highly emissive π-conjugated macrocycles with tunable circularly polarized luminescence
(CPL) have sparked theoretical and synthetic interests in recent years. Herein, we report a …

The supramolecular chemistry of strained carbon nanohoops

Y Xu, M von Delius - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Since 1996, a growing number of strained macrocycles, comprising only sp2‐or sp‐
hybridized carbon atoms within the ring, have become synthetically accessible, with the [n] …

Fundament and application of graphdiyne in electrochemical energy

Y Du, W Zhou, J Gao, X Pan, Y Li - Accounts of Chemical …, 2020 - ACS Publications
Conspectus The artificial synthesis of graphdiyne (GDY) in 2010 successfully fills the blank
of low temperature preparation of all-carbon allotropes. GDY is an emerging two …