Recent Advances in Dearomative Partial Reduction of Benzenoid Arenes

DH Liu, J Ma - Angewandte Chemie International Edition, 2024 - Wiley Online Library
Dearomative partial reduction is an extraordinary approach for transforming benzenoid
arenes and has been well‐known for many decades, as exemplified by the dehydrogenation …

Site-selective C (sp3)-H Functionalization of Primary Aliphatic Amines

Y Tao, K Guo, H Chen, G Yan, M Guo - Organic Chemistry Frontiers, 2024 - pubs.rsc.org
The CH bond functionalization represents one of the most efficient and straightforward
strategies to diversify the existing molecules. It is the most challenging task to achieve the …

Visible-Light-Induced Redox-Neutral Difunctionalization of Alkenes and Alkynes

S Mondal, S Ghosh, A Hajra - Chemical Communications, 2024 - pubs.rsc.org
The twelve principles of green chemistry illuminate the pathway in the direction of
sustainable and eco-friendly synthesis, marking a fundamental shift in synthetic organic …

Photosensitized 1, 2-Difunctionalization of Alkenes to Access β-Amino Sulfonamides

ZL Xiao, ZZ Xie, CP Yuan, KY Deng, K Chen… - Organic …, 2024 - ACS Publications
A metal-free photosensitized 1, 2-imino-sulfamoylation of olefins by employing a tailor-made
sulfamoyl carbamate as the difunctionalization reagent has been established. This protocol …

Access to 4‐Membered Heterocycles via Visible‐Light Triggered Intramolecular Cyclization from Alkynes: Bypassing Unfavorable 4‐endo‐dig Cyclization

A Sharma, A Choi, D Yim, H Kim… - Advanced Synthesis & …, 2024 - Wiley Online Library
We describe a catalyst, oxidant, and coupling‐reagent free strategy to access 4‐membered
heterocycles, representing a unique example of visible‐light triggered intramolecular …

Recent Advances in Strategies for Halide Atom Transfer (XAT) and Their Applications

J Yifeng, Y Yanli, J Zhiyong - Chinese Journal of Organic Chemistry, 2024 - sioc-journal.cn
Following the rapid advance of radical chemistry, a range of halogen atom transfer (XAT)
reagents have been developed by chemists for alkyl and aryl halides, which typically feature …

卤素原子转移(XAT) 策略及应用新进展

蒋译锋, 尹艳丽, 江智勇 - 有机化学 - sioc-journal.cn
摘要随着自由基化学的发展, 对于具有较强键能且高氧化还原电位的烷基和芳基卤化物,
化学家们开发了一系列卤素原子转移(XAT) 试剂. 这些试剂通过自由基取代途径攫取烷基和芳基 …

Cooperative NHC and Photoredox Catalyzed Radical Aminoacylation of Alkenes to Tetrahydropyridazines

WD Liu, J Gao, JN Mo, Y Zhou, J Zhao - Chemistry–A European … - Wiley Online Library
Tetrahydropyridazines constitute an important structural motif found in numerous natural
products and pharmaceutical compounds. Herein, we report an aminoacylation reaction of …

Modern Photo-and Electrochemical Approaches to Aryl Radical Generation

K Grudzień, A Zlobin, J Zadworny, K Rybicka-Jasińska… - 2024 - chemrxiv.org
Aryl rings appear in a plethora of natural products or drugs. A vast majority of arylation
processes still rely on the utilization of transition-metal complexes as catalysts. Another …