The synthesis of metallaisoxazole by the [3+ 2] cycloaddition reaction of
metallacyclopropene with nitrosonium tetra-fluoroborate has been achieved under mild …

Bulky substituents play important roles in controlling the reaction pathways or producing
selected products. This work reports that the shift of metallafuran rings in a …

Cycloaddition reactions of carbynes in metallacycles with π-bond substrates have been
rarely reported. We report the first [2+ 2] cycloaddition of metallapentalynes with …

The term “carbolong complexes” represents a series of novel π-conjugating aromatic
frameworks, which are formed by the chelation of a carbon chain (carbolong ligand) …

Investigating the correlations of electron transport between multiple channels shows vital
promises for the design of molecule‐scale circuits with logic operations. To control the …

摘要碳龙配合物由一条碳数不少于7 的碳链配体鳌合过渡金属而成, 代表了一系列全新的π
共轭分子骨架基元, 并表现出独特的光物理性质, 具有很好的应用前景. 通过合理设计多炔化合物 …

摘要钳形金属配合物因其独特的结构, 性质和应用引起了化学家的广泛关注.
然而该类配合物大部分都是以2~ 3 个杂原子(基团) 与金属原子配位. 只有极少数例子同时具有3 …

In this work, we describe a method of controlling the size of a conducting polymer (CP)
junction between one ultramicroelectrode (UME) and a substrate electrode using a scanning …

Abstract Treatment of the SiMe3‐protected dichloro‐rhenium carbyne complexes Re {≡
CCH= C (R) C≡ CSiMe3} Cl2 (PMe2Ph) 3 (R= CMe3, 1‐adamantyl) with CsF in methanol …

Due to the linear property around an acetylenic carbon, the introduction of such an atom to a
small cycle would result in high ring strain. Currently, the smallest isolated rings are five …