Silver‐Based Radical Reactions: Development and Insights

G Fang, X Cong, G Zanoni, Q Liu… - Advanced Synthesis & …, 2017 - Wiley Online Library
Silver‐mediated reactions have recently emerged as a frontier area in organic chemistry.
Indeed, the remarkable property of silver as a single‐electron oxidant has led to its …

Uses of K2S2O8 in Metal-Catalyzed and Metal-Free Oxidative Transformations

S Mandal, T Bera, G Dubey, J Saha, JK Laha - ACS Catalysis, 2018 - ACS Publications
Carbon–carbon/carbon–heteroatom bond formation via oxidative transformations is a
heavily explored topic at the frontier of chemistry. Potassium persulfate (K2S2O8) has …

Mn-catalyzed electrooxidative undirected C–H/P–H cross-coupling between aromatics and diphenyl phosphine oxides

S Wang, Q Xue, Z Guan, Y Ye, A Lei - ACS Catalysis, 2021 - ACS Publications
C–P bonds are widely found in a great many bioactive compounds and functional
molecules. Transition-metal-catalyzed dehydrogenative C–H/P–H cross-coupling plays a …

Recent advances of transition metal-catalyzed PC coupling reactions

C Shao, W Xu, L Li, X Zhang - Chinese Journal of Organic Chemistry, 2017 - sioc-journal.cn
Organophosphorus compounds which contain PC bonds have been widely used in
photoelectric materials, retardant materials and medicinal chemistry. It is an important …

Direct C− H Phosphonylation of Electron‐Rich Arenes and Heteroarenes by Visible‐Light Photoredox Catalysis

RS Shaikh, I Ghosh, B König - Chemistry–A European Journal, 2017 - Wiley Online Library
The direct transformation of ubiquitous, but chemically inert C− H bonds into diverse
functional groups is an important strategy in organic synthesis that improves the atom …

Ruthenium (II)-catalyzed para-selective CH difluoroalkylation of aromatic aldehydes and ketones using transient directing groups

Y Cheng, Y He, J Zheng, H Yang, J Liu, G An… - Chinese Chemical …, 2021 - Elsevier
A Ru (II)-catalyzed para-difluoroalkylation of aromatic aldehydes and ketones with a
transient directing group has been developed. It utilizes less expensive ruthenium catalysts …

Silver-catalyzed decarboxylative cyclization for the synthesis of substituted pyrazoles from 1, 2-diaza-1, 3-dienes and α-keto acids

S Katiyar, A Kumar, KV Sashidhara - Chemical Communications, 2022 - pubs.rsc.org
A silver-catalyzed decarboxylative cyclization process has been developed for the synthesis
of substituted pyrazoles from the readily available 1, 2-diaza-1, 3-dienes and α-keto acids …

Straightforward synthesis of functionalized chroman-4-ones through cascade radical cyclization-coupling of 2-(allyloxy) arylaldehydes

J Zhao, P Li, X Li, C Xia, F Li - Chemical Communications, 2016 - pubs.rsc.org
A novel and direct approach to synthesize a series of phosphonate, azide and hydroxy
functionalized chroman-4-ones has been developed. The cascade transformation appears …

Silver (i)-promoted C5–H phosphonation of 8-aminoquinoline amides with H-phosphonates

M Sun, S Sun, H Qiao, F Yang, Y Zhu, J Kang… - Organic Chemistry …, 2016 - pubs.rsc.org
A simple and efficient protocol for silver (I)-promoted phosphonation of 8-aminoquinoline
amides with dialkyl H-phosphonates has been developed, affording the desired products in …

Dehydrogenative coupling involving P (O)–H bonds: a powerful way for the preparation of phosphoryl compounds

T Chen, JS Zhang, LB Han - Dalton Transactions, 2016 - pubs.rsc.org
Because of the unique properties and wide applications, continuing efforts have been
devoted to developing simpler and cleaner methods for the synthesis of organophosphorus …