Metallic Cu in the presence of an amine ligand has become very popular as a catalyst in
reversible-deactivation radical polymerization (RDRP). Two contrasting mechanisms were …

This article is the second part of a mechanistic study regarding the role of Cu (0) and CuBr
during the Cu (0)-mediated polymerization in organic and aqueous media with the aim of …

The synthesis of well-defined α, ω-dihydroxyl telechelic multiblock copolymers by sequential
in situ chain extensions via aqueous Cu (0) mediated living radical polymerization (SET …

Nanomaterial-based hybrid devices have demonstrated potential use in environmental
contaminant sensing. Polymer thin films are tunable in their physicochemical properties …

The Cu (0)-mediated reversible deactivation radical polymerization of N, N′-
dimethylaminoethyl acrylate in DMSO and IPA at ambient temperature using Cu (0) wire is …

Since its invention 25 years ago, atom transfer radical polymerization has become one of the
most dominant methods in controlled radical polymerization. This rise in importance is due …

The in-depth understanding of the kinetics and mechanism of conventional and reversible
deactivation radical polymerization (RDRP) strategies requires efficient techniques to attain …

A comprehensive kinetic model based on the mechanism of supplemental activator and
reducing agent atom transfer radical polymerization (SARA ATRP) was developed to better …

Polymer chain growth can be controlled in a spatiotemporal manner by external stimuli
including chemical, redox, light, electrical current, and mechanical procedures. In this paper …

Polymerization of multifunctional monomers could produce polymers with different
functionalities and novel macromolecular architectures. However, the ability to control the …