Coordination versatility of NHC-metal topologies in asymmetric catalysis: Synthetic insights and recent trends

A Jayaraj, AV Raveedran, AT Latha… - Coordination Chemistry …, 2023 - Elsevier
Asymmetric metal based catalysis has advanced quickly in recent years, with its efficiency
relying exclusively on chiral ligands. Rational design and meticulous selection of chiral …

What about the progress in the synthesis of flavonoid from 2020?

ZQ Liu - European Journal of Medicinal Chemistry, 2022 - Elsevier
Flavonoids are a well-known family of natural polyphenols because of their prevalent
properties in the physiological and medicinal field. In addition to a plethora of natural …

Nickel‐Catalyzed Asymmetric Hydrogenation of α‐Substituted Vinylphosphonates and Diarylvinylphosphine Oxides

H Wei, H Chen, J Chen, ID Gridnev… - Angewandte Chemie …, 2023 - Wiley Online Library
Chiral α‐substituted ethylphosphonate and ethylphosphine oxide compounds are widely
used in drugs, pesticides, and ligands. However, their catalytic asymmetric synthesis is still …

Transition Metal‐Catalyzed Enantioselective Synthesis of Chiral Five‐ and Six‐Membered Benzo O‐heterocycles

L Yang, X Liang, Y Ding, X Li, X Li… - The Chemical …, 2023 - Wiley Online Library
Enantiomerically enriched five‐and six‐membered benzo oxygen heterocycles are
privileged architectures in functional organic molecules. Over the last several years, many …

Ru (II)-Catalyzed Asymmetric Transfer Hydrogenation of Chalcones in Water: Application to the Enantioselective Synthesis of Flavans BW683C and Tephrowatsin E

FC Demidoff, GS Caleffi, M Figueiredo… - The Journal of Organic …, 2022 - ACS Publications
The oxo-tethered-Ru (II) precatalyst promoted the one-pot C═ C/C═ O reduction of
chalcones using sodium formate as the hydrogen source in water through asymmetric …

Asymmetric Hydrogenation by Relay Catalysis with FLPs and CPAs: Stereodivergent Synthesis of 3-Substituted Flavanones

J Chen, W Meng, X Feng, H Du - The Journal of Organic …, 2022 - ACS Publications
To access flavanones bearing two contiguous stereogenic centers, a metal-free asymmetric
hydrogenation of racemic 3-alkylidene flavanones has been developed by relay catalysis …

Asymmetric Transfer Hydrogenation of 2, 3-Disubstituted Flavanones through Dynamic Kinetic Resolution Enabled by Retro-Oxa-Michael Addition: Construction of …

QX Xie, LX Liu, ZH Zhu, CB Yu… - The Journal of Organic …, 2022 - ACS Publications
A ruthenium-catalyzed asymmetric transfer hydrogenation of 2, 3-disubstituted flavanones
was developed for the construction of three contiguous stereocenters under basic conditions …

Regio-and Stereoselective Transfer Hydrogenation of Aryloxy Group-Substituted Unsymmetrical 1, 2-Diketones: Synthetic Applications and Mechanistic Studies

W Liu, C Ren, L Zhou, H Luo, X Meng… - Journal of the …, 2024 - ACS Publications
Developing a general method that leads to the formation of different classes of chiral
bioactive compounds and their stereoisomers is an attractive but challenging research topic …

Copper-Catalyzed Intramolecular Aldehyde–Ketone Nucleophilic Additions for the Synthesis of Chromans Bearing a Tertiary Alcohol Motif

C Zhu, W Jiang, D Ma - The Journal of Organic Chemistry, 2023 - ACS Publications
The synthesis of chroman-3-ol derivatives via intramolecular nucleophilic additions has
been established. Aldehydes can be used as alkyl carbanion equivalents via reductive …

Advances in the synthesis of rearranged homoisoflavonoids

FC Demidoff, PRR Costa, GS Caleffi - Organic & Biomolecular …, 2024 - pubs.rsc.org
Rearranged homoisoflavonoids constitute a unique group of natural products, renowned for
their structural diversity and complexity. These compounds, derived from modifications in the …