In recent decades, the traceless nature of visible photons has been exploited for the
development of efficient synthetic strategies for the photoconversion of colourless …

Advances in site-selective molecular editing have enabled structural modification on
complex molecules. However, thus far, their applications have been restricted to C–H …

Despite the significant achievements in dearomatization and C–H functionalization of
arenes, the arene ring-opening remains a largely unmet challenge and is underdeveloped …

The skeletal editing of azaarenes through insertion, deletion, or swapping of single atoms
has recently gained considerable momentum in chemical synthesis. Here, we describe a …

The one‐pot synthesis of λ4‐dibenzothiophen‐5‐imino‐N‐dibenzothiophenium triflate (1) in
multigram scale is reported. This compound reacts with Rh2 (esp) 2 (esp= α, α, α′, α …

The synthesis of pyridines from dinitrogen in homogeneous solution is known to be
challenging considering that an N2 cleavage step needs to be combined with two N–C …

Pyridines are valuable pharmacophores, and their access via direct and selective
transmutation of carbon atom with desired nitrogen could become crucial in drug discovery …

Reactions that change the identity of an atom within a ring system are emerging as valuable
tools for the site-selective editing of molecular structures. Herein, we describe the expansion …

In this report, we present a photopromoted, metal-free transannulation of phenyl azides for
the synthesis of DNA-encoded seven-membered rings. The transformation is efficiently …

Fluorinated quinolines and pyridines are prevalent pharmacophores, yet their synthesis is
often challenging. Herein, we demonstrate that dibromofluoromethane as …