Palladium (II)-Catalyzed Intramolecular [2+ 2+ 2] Annulation of Indolyl 1, 3-Diynes: Construction of Azepino-Fused Carbazoles

ML Yao, XY Wang, GC Feng, JK Liu, B Wu… - Organic …, 2023 - ACS Publications
A novel palladium (II)-catalyzed intramolecular [2+ 2+ 2] annulation of indolyl 1, 3-diynes is
described in this contribution. A variety of azepino-fused carbazoles are obtained in …

[HTML][HTML] Update on novel synthetic approaches towards the construction of carbazole nuclei: a review

S Munawar, AF Zahoor, A Mansha, TH Bokhari… - RSC advances, 2024 - pubs.rsc.org
The carbazole scaffold is a significant entity in organic compounds due to its variety of
biological and synthetic applications. Traditionally, carbazole skeletons have been …

Controllable cyclization of alkynyl thioethers via Brønsted acid-catalyzed dearomatization

XY Fan, X Liu, YZ Kong, BH Zhu, J Lin… - Organic Chemistry …, 2023 - pubs.rsc.org
An efficient Brønsted acid-catalyzed formal alkyne hydroarylation of phenol-alkynyl
thioethers via dearomatization and rearrangement is described. This protocol enables …

Cascade hydroarylation/Diels–Alder cycloaddition of alkynylindoles with electron-deficient alkynes and alkenes

GC Feng, JC Li, X Huang, JK Liu, B Wu… - Chemical …, 2024 - pubs.rsc.org
Herein, a novel cascade gold (I)-catalyzed hydroarylation of alkynylindoles and subsequent
Diels–Alder cycloaddition with electron-deficient alkynes and alkenes is described. A variety …

Hydroarylation of alkynes via dual ortho-C–H functionalization of diaryl amines on a dicopper (i, i) platform

NK Pal, M Patra, PK Pandey, JK Bera - Chemical Communications, 2023 - pubs.rsc.org
A pyridine and morpholine-functionalized dicopper (I, I)-NHC complex (1) features both
terminal and bridging coordination modes of NHC within the same molecule, and catalyzes …

Electrochemical dehydrogenative cyclization/aromatization of aniline-tethered alkylidenecyclopropanes: facile access to benzo [c] carbazoles

ZJ Huang, JH Qin, ML Huang, Q Sun, HY Xie… - Organic Chemistry …, 2023 - pubs.rsc.org
A novel noble transition metal-and external oxidant-free electrochemical cyclization/
aromatization of aniline-tethered alkylidenecyclopropanes enabled by N–H/C–H …

Photocatalytic Thio/Selenosulfonylation–Bicyclization of Indole-Tethered 1,6-Enynes Leading to Substituted Benzo[c]pyrrolo[1,2,3-lm]carbazoles

HD Zuo, X Chen, Y Zhang, JW Liu, SH Yan, G Li… - Organic …, 2024 - ACS Publications
The photocatalyzed radical-triggered thio/selenosulfonylation–bicyclization of indole-
tethered 1, 6-enynes has been established for the first time, enabling the synthesis of …

TMSOTf-Promoted Cyclization of Indole-2-methyl-α-aminoketones: Access to 4-Aryl-Substituted β-Carbolines

XY Yang, JM Yang, B Wu - Organic Letters, 2024 - ACS Publications
An efficient method to construct 4-aryl-substituted β-carbolines from indole-2-methyl-α-
aminoketones via a TMSOTf-promoted annulation reaction was reported. High yield along …

Phosphine‐Catalyzed [4+ 3] Annulation Reaction of Indole Derivatives with MBH Carbonates: A Facile Access to Indole‐1, 2‐fused 1, 4‐Diazepinones and Azepines

Y Zhu, H Jiang, YN Wang - Chinese Journal of Chemistry, 2024 - Wiley Online Library
Comprehensive Summary A phosphine‐catalyzed [4+ 3] annulation between dinucleophilic
indole derivatives and Morita− Baylis− Hillman (MBH) carbonates was discovered by using …

Seven-membered rings

BC Hawkins, AC Bissember, SM Wales… - Progress in Heterocyclic …, 2024 - Elsevier
Progress in the synthesis of seven-membered heterocycles bearing up to and including
three N, O, or S heteroatoms continues unabated. The application of classical ring …